Glazing comprising a substrate coated with a stack comprising at least one functional layer made from zinc-doped silver
A glazing includes a transparent substrate coated with a stack of thin layers including at least one functional metal layer and at least two antireflective coatings, each antireflective coating including at least one dielectric layer, so that each functional metal layer is positioned between two antireflective coatings. The stack includes at least one silver-based functional metal layer including at least 95.0% by weight of silver, with respect to the weight of the functional layer, and from 0.5 to 3.5% by weight of zinc, with respect to the weight of zinc and silver in the functional layer.
1. A glazing comprising a transparent substrate coated with a stack of layers comprising at least one functional metal layer and at least two antireflective coatings, each antireflective coating comprising at least one dielectric layer, so that each functional metal layer is positioned between two antireflective coatings, wherein the stack comprises at least one silver-based functional metal layer consisting of:
at least 96.5% by weight of silver, with respect to the weight of the functional layer, and
from 0.5 to 3.5% by weight of zinc, with respect to the weight of zinc and silver in the functional layer.
2. The glazing as claimed in claim 1 , wherein the stack comprises at least one antireflective coating comprising a dielectric layer capable of generating defects of dome type.
3. The glazing as claimed in claim 2 , wherein the dielectric layer capable of generating defects of dome type is based on zinc tin oxide.
4. The glazing as claimed in claim 1 , wherein the stack does not comprise an antireflective coating comprising a dielectric layer capable of generating defects of hole type chosen from layers based on titanium oxide, on niobium oxide and on tin oxide.
5. The glazing as claimed in claim 1 , wherein the stack comprises one or more titanium-comprising layers and wherein the silver-based functional metal layer is separated by at least 10 nm from each of the one or more titanium-comprising layers.
6. The glazing as claimed in claim 5 , wherein the silver-based functional metal layer is separated by at least 20 nm from each of the one or more titanium-comprising layers.
7. The glazing as claimed in claim 1 , wherein the stack comprises at least one blocking layer located above and immediately in contact with the silver-based functional metal layer.
8. The glazing as claimed in claim 7 , wherein the blocking layer is a layer based on NiCr, NiCrN, NiCrO x , NiO or NbN.
9. The glazing as claimed in claim 1 , wherein one of the at least two antireflective coatings comprises a dielectric layer capable of generating defects of dome type that is located below a silver-based functional metal layer.
10. The glazing as claimed in claim 1 , wherein the antireflective coating located below the silver-based functional metal layer comprises at least one dielectric layer having a stabilizing function immediately in contact with a blocking layer.
11. The glazing as claimed in claim 10 , wherein the at least one dielectric layer having a stabilizing function immediately in contact with the blocking layer is based on zinc oxide, optionally doped using at least one other element.
12. The glazing as claimed in claim 11 , wherein the at least one other element is aluminum.
13. The glazing as claimed in claim 1 , wherein the stack comprises:
an antireflective coating located below the silver-based functional metal layer comprising at least one dielectric layer based on zinc tin oxide and a dielectric layer having a stabilizing function based on zinc oxide,
a functional metal layer based on silver comprising zinc located immediately in contact with the dielectric layer having a stabilizing function based on zinc oxide,
optionally a blocking overlayer,
an antireflective coating located above the silver-based functional metal layer, and
optionally an upper protective layer.
14. The glazing as claimed in claim 1 , wherein the thickness of a functional metal layer is between 5 and 20 nm.
15. The glazing as claimed in claim 1 , wherein the antireflective coatings comprise at least one dielectric layer having a barrier function based on silicon compounds chosen from oxides, silicon nitrides Si 3 N 4 and oxynitrides SiO x N y , optionally doped using at least one other element.
16. The glazing as claimed in claim 15 , wherein the silicon compound is SiO 2 .
17. The glazing as claimed in claim 15 , wherein the at least one other element is aluminum.
18. The glazing as claimed in claim 1 , wherein the substrate coated with the stack has been subjected to a heat treatment at a temperature of greater than 300° C.
19. The glazing as claimed in claim 18 , wherein the substrate coated with the stack has been subjected to a heat treatment at a temperature of greater than 500° C.
20. The glazing as claimed in claim 1 , wherein at least the substrate coated with the stack is made of bent or tempered glass.
21. The glazing as claimed in claim 1 , wherein the at least one silver-based functional metal layer comprises at least 98.0% by weight of silver, with respect to the weight of the functional layer.
22. The glazing as claimed in claim 1 , wherein the at least one silver-based functional metal layer comprises from 1.0 to 2.0% by weight of zinc, with respect to the weight of zinc and silver in the functional layer.