Method for preparing hydroxyethyl (meth) acrylate
Hydroxyethyl (methyl)acrylate is prepared by a process of a combination of a three-stage tubular reactor and a tower reactor, wherein, firstly, a catalyst, a polymerization inhibitor and (methyl) acrylic acid are mixed until the solids are dissolved, then mixed with a part of ethylene oxide and thereafter enter into a first tubular reactor for a reaction, a reaction liquid flowing out from the first tubular reactor is mixed with a certain amount of ethylene oxide and enters into a second tubular reactor for a reaction, a reaction liquid flowing out from the second tubular reactor is then mixed with a certain amount of ethylene oxide and thereafter enters into a third tubular reactor, and a reaction liquid flowing out from the third tubular reactor is then passed through a stage of an adiabatic tower reactor and aged such that a product liquid is obtained from extraction.
1. A method for preparing hydroxyethyl (meth)acrylate, conducted in a process using a combination of three-stage tubular reactors and a tower reactor, the process comprising the following steps:
firstly, mixing catalysts, polymerization inhibitors and (meth)acrylic acid until the solids are dissolved;
then mixing the mixture of the catalysts, polymerization inhibitors and (meth)acrylic acid with ethylene oxide in an amount of 30-80% of the total amount of the ethylene oxide in the whole reaction and thereafter entering a first tubular reactor to react;
mixing the reaction liquid from the first tubular reactor with ethylene oxide in an amount of 10-50% of the total amount of the ethylene oxide in the whole reaction and thereafter entering a second tubular reactor to react;
mixing the reaction liquid from the second tubular reactor with ethylene oxide in an amount of 1-30% of the total amount of the ethylene oxide in the whole reaction and thereafter entering a third tubular reactor; and
aging the reaction liquid from the third tubular reactor in a tower reactor to obtain hydroxyethyl (meth)acrylate liquid product.
2. The method according to claim 1 , wherein for the whole reaction, the molar ratio of the total amount of ethylene oxide to (meth)acrylic acid is 1.0-1.2:1.
3. The method according to claim 1 , wherein the polymerization inhibitors are selected from one or more of p-benzoquinone, p-phenylenediamine, phenothiazine, diisopropyl p-phenylene diamine, 4-hydroxy-2,2,6,6-tetramethyl-piperidinooxy and 4-carbonyl-2,2,6,6-tetramethyl-piperidinooxy; the amount of the polymerization inhibitors is 0.01-0.2% of the weight of (meth)acrylic acid.
4. The method according to claim 1 , wherein the catalysts are one or more of amine compounds, iron compounds and chromium compounds; the amine compound is selected from tetrabutyl ammonium bromide, tetramethyl ammonium bromide, tetramethyl ammonium chloride, tetrabutyl ammonium iodide, triethylamine and pyridine; the iron compound is selected from ferric trichloride, iron powder, ferric formate, ferric acetate, iron acrylate and iron methacrylate; the chromium compound is selected from chromium trichloride, chromium acrylate, chromium methacrylate, chromium acetylacetonate, chromium picolinate, chromium formate, chromium acetate; the amount of the catalysts is 0.1-2% of the weight of (meth)acrylic acid.
5. The method according to claim 1 , wherein the amount of the ethylene oxide added into the first tubular reactor is 50-70% of the total amount of the ethylene oxide in the whole reaction; the amount of the ethylene oxide added into the second tubular reactor is 20-40% of the total amount of the ethylene oxide in the whole reaction; the amount of the ethylene oxide added into the third tubular reactor is 5-20% of the total amount of the ethylene oxide in the whole reaction.
6. The method according to claim 1 , in the first tubular reactor, the reaction temperature is 80-120° C., the reaction pressure is 0.2-0.5 Mpa, and the residence time is 0.1-0.3 h.
7. The method according to claim 1 , in the second tubular reactor, the reaction temperature is 100-130° C., the reaction pressure is 0.4-0.8 Mpa and the residence time is 0.2-0.5 h.
8. The method according to claim 1 , in the third tubular reactor, the reaction temperature is 110-150° C., the reaction pressure is 0.5-1 Mpa, and the residence time is 0.25-0.6 h.
9. The method according to claim 1 , during the reaction, each of the tubular reactors is under the protection of N 2 .
10. The method according to claim 1 , wherein the tower reactor is an adiabatic tower reactor.
11. The method according to claim 1 , wherein the theoretical plate number of the tower reactor is 4-20; the reaction pressure is 0.8-1.2 Mpa; the residence time is 0.3-1 h.
12. The method according to claim 2 , wherein the polymerization inhibitors are selected from one or more of p-benzoquinone, p-phenylenediamine, phenothiazine, diisopropyl p-phenylene diamine, p-hydroxy tetramethyl piperidine nitrogen oxygen free radical and p-carbonyl tetramethyl piperidine nitrogen oxygen free radical; the amount of the polymerization inhibitors is 0.01-0.2% of the weight of (meth)acrylic acid.
13. The method according to claim 2 , wherein the catalysts are one or more of amine compounds, iron compounds and chromium compounds; the amine compound is selected from tetrabutyl ammonium bromide, tetramethyl ammonium bromide, tetramethyl ammonium chloride, tetrabutyl ammonium iodide, triethylamine and pyridine; the iron compound is selected from ferric trichloride, iron powder, ferric formate, ferric acetate, iron acrylate and iron methacrylate; the chromium compound is selected from chromium trichloride, chromium acrylate, chromium methacrylate, chromium acetylacetonate, chromium picolinate, chromium formate, chromium acetate; the amount of the catalysts is 0.1-2% of the weight of (meth)acrylic acid.
14. The method according to claim 2 , wherein the amount of the ethylene oxide added into the first tubular reactor is 50-70% of the total amount of the ethylene oxide in the whole reaction; the amount of the ethylene oxide added into the second tubular reactor is 20-40% of the total amount of the ethylene oxide in the whole reaction; the amount of the ethylene oxide added into the third tubular reactor is 5-20% of the total amount of the ethylene oxide in the whole reaction.
15. The method according to claim 2 , in the first tubular reactor, the reaction temperature is 80-120° C., the reaction pressure is 0.2-0.5 Mpa, and the residence time is 0.1-0.3 h.
16. The method according to claim 2 , in the second tubular reactor, the reaction temperature is 100-130° C., the reaction pressure is 0.4-0.8 Mpa, and the residence time is 0.2-0.5 h.
17. The method according to claim 2 , in the third tubular reactor, the reaction temperature is 110-150° C., the reaction pressure is 0.5-1 Mpa, and the residence time is 0.25-0.6 h.
18. The method according to claim 5 , in the first tubular reactor, the reaction temperature is 80-120° C., the reaction pressure is 0.2-0.5 Mpa, and the residence time is 0.1-0.3 h.
19. The method according to claim 5 , in the second tubular reactor, the reaction temperature is 100-130° C., the reaction pressure is 0.4-0.8 Mpa, and the residence time is 0.2-0.5 h.
20. The method according to claim 5 , in the third tubular reactor, the reaction temperature is 110-150° C., the reaction pressure is 0.5-1 Mpa, and the residence time is 0.25-0.6 h.
21. The method according to claim 2 , wherein for the whole reaction, the molar ratio of the total amount of ethylene oxide to (meth)acrylic acid is 1.03-1.1:1.
22. The method according to claim 6 , in the first tubular reactor, the reaction temperature is 90-110° C., the reaction pressure is 0.3-0.4 Mpa and the residence time is 0.15-0.25 h.
23. The method according to claim 7 , in the second tubular reactor, the reaction temperature is 110-120° C., the reaction pressure is 0.5-0.7 Mpa and the residence time is 0.25-0.4 h.
24. The method according to claim 8 , in the third tubular reactor, the reaction temperature is 120-130° C., the reaction pressure is 0.6-0.9 Mpa and the residence time is 0.3-0.5 h.