Bromine-facilitated synthesis of fluoro-sulfur compounds
Described herein are methods for the bromine-facilitated synthesis of fluoro-sulfur compounds, that include SF 4 , SF 5 Cl, SF 5 Br and SF 6 . The methods described herein generally require lower temperature and pressure, produce higher yields, require less time, do not use corrosive or costly reactants and solvents that are commonly used in the synthesis of the fluoro-sulfur compounds, and do not produce deleterious waste products when compared to previously-used methods.
1. A method of producing SF 4 comprising: admixing a sulfur reactant, KF, and Br 2 , wherein:
the sulfur reactant, the KF, and the Br 2 react at temperatures from about 10° C. to about 27° C.;
the reaction is within about 10% of completion in less than about 3 days; and
the sulfur reactant, the KF, and the Br 2 react to produce the SF 4 in the absence of reaction solvents.
2. A method according to claim 1 , wherein the sulfur reactant is S, S 2 Cl 2 , SCl 2 , S 2 Br 2 , SBr 2 , or a combination thereof.
3. A method of producing SF 4 comprising: admixing a sulfur reactant, KF, Cl 2 , and Br 2 , wherein:
the sulfur reactant, the KF, the Cl 2 , and the Br 2 react at temperatures from about 10° C. to about 27° C.;
the reaction is within about 10% of completion in less than about 3 days; and
the sulfur reactant, the KF, the Cl 2 , and the Br 2 react to produce the SF 4 in the absence of reaction solvents.
4. A method according to claim 3 , wherein the sulfur reactant is S, S 2 Cl 2 , SCl 2 , S 2 Br 2 , SBr 2 , or a combination thereof.
5. A method according to claim 1 , wherein the sulfur reactant is S.
6. A method according to claim 1 , wherein the sulfur reactant, the KF, and the Br 2 react to produce the SF 4 at a yield of at least 10%.
7. A method according to claim 1 , wherein the sulfur reactant, the KF, and the Br 2 react to produce the SF 4 at a yield from about 57% to about 96%.
8. A method according to claim 3 , wherein the sulfur reactant is S.
9. A method of producing SF 4 comprising: admixing a sulfur reactant, KF, and Br 2 , wherein:
the sulfur reactant, the KF, and the Br 2 react at temperatures from about 27° C. to about 80° C.;
the reaction provides a yield of SF 4 within about 57% to about 96% in less than about 1 day; and
the sulfur reactant, the KF, and the Br 2 react to produce the SF 4 in the absence of reaction solvents.
10. A method according to claim 9 , wherein the sulfur reactant is S.
11. A method of producing SF 4 comprising: admixing a sulfur reactant, KF, and Br 2 , wherein:
the sulfur reactant, the KF, and the Br 2 react at temperatures from about 10° C. to about 115° C.;
the reaction provides a yield of SF 4 within about 57% to less than 100%; and
the sulfur reactant, the KF, and the Br 2 react to produce the SF 4 in the absence of reaction solvents.
12. A method according to claim 11 , wherein the sulfur reactant, the KF, and the Br 2 produce SF 4 at temperatures from about 10° C. to about 40° C.
13. A method according to claim 11 , wherein the sulfur reactant, the KF, and the Br 2 produce SF 4 at temperatures from about 10° C. to about 27° C.
14. A method according to claim 11 , wherein the sulfur reactant, the KF, and the Br 2 produce SF 4 at temperatures from about 27° C. to about 115° C.
15. A method according to claim 11 , wherein the yield of SF 4 is from about 57% to about 96%.