Active energy ray-curable inkjet ink and ink set
The present disclosure relates to an active energy ray curable inkjet ink for use in a single pass printing inkjet system, the inkjet ink containing a colorant, a monomer and at least one initiator, wherein the sum of the integrated value(s) of absorbance across wavelengths from 380 to 410 nm of the initiator(s) is at least 35, and 0.02≦amount of initiator/amount of monomer≦0.50 (weight ratio) is satisfied. The disclosure also relates to an ink set including the ink. The present disclosure is able to show printed articles that exhibit no wrinkling or tack, excellent color reproducibility, and reduced amounts of residual components within the cured film of printed articles, while offering high productivity, and can also show an active energy ray-curable inkjet ink cured film which has a low residue ratio and is of low-odor, while exhibiting similar print quality and productivity to existing printing systems.
1. A method for producing an active energy ray-curable inkjet ink cured film which uses an active energy ray-curable inkjet ink for use in a single pass printing inkjet system, comprising curing an active energy ray-curable inkjet ink, wherein
the active energy ray-curable inkjet ink comprises a colorant, monomers, and at least one initiator,
wherein 0.02≦amount of initiator/amount of monomer≦0.16 (weight ratio) is satisfied,
the monomers comprise a difunctional monomer having ethylene oxide or propylene oxide as the main backbone, wherein the difunctional monomer is in an amount of from 50 to 100% by weight of the total monomer component,
the difunctional monomer comprises 2-(2-vinyloxyethoxy)ethyl acrylate (VEEA) in an amount of 10 to 60% by weight relative to the total weight of the active energy ray-curable inkjet ink,
the monomers comprise a monomer having a molecular weight of not more than 300, and further comprise a monomer having a molecular weight of more than 300 in an amount of 15% by weight or less relative to the total weight of the active energy ray-curable inkjet ink, and
the initiator comprises at least bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide,
the viscosity of the active energy ray-curable inkjet ink at 25° C. is not more than 20 mPa·s, and
the active energy ray-curable inkjet ink is cured with irradiation of the active energy rays under an atmosphere in which an oxygen concentration is less than an oxygen concentration in open air, wherein the oxygen concentration in the atmosphere during the irradiation of the active energy ray is from 0.5 to 10% by volume.
2. The method for producing the active energy ray-curable inkjet ink cured film according to claim 1 , wherein the monomer comprises a polyfunctional monomer and optionally a monofunctional monomer and satisfies 0≦amount of the monofunctional monomer/amount of the polyfunctional monomer ≦0.2 (weight ratio).
3. The method for producing the active energy ray-curable inkjet ink cured film according to claim 1 , wherein the ink is cured using a light source having an emission intensity local maximum within a wavelength range from 300 to 450 nm.
4. The method for producing the active energy ray-curable inkjet ink cured film according to claim 1 , wherein the ink is cured using at least a light source having an emission intensity local maximum at a wavelength of 380 nm or higher.
5. The method for producing the active energy ray-curable inkjet ink cured film according to claim 3 , wherein the light source is a combination of a light source having an emission intensity local maximum at a wavelength of at least 380 nm but less than 450 nm, and a light source having an emission intensity local maximum at a wavelength of at least 300 nm but less than 380 nm.
6. The method for producing the active energy ray-curable inkjet ink cured film according to claim 1 , wherein the initiator further comprises at least one compound selected from the group consisting of 2-benzyl-2-dimethylamino-1(4-morpholinophenyl)-butanone-1, 2,4,6-trimethylbenzoyldiphenylphosphine oxide, oligo[2-hydroxy-2-methyl-1-{4-(1-methylvinyl)phenyl}propanone] and 4,4′-diethylaminobenzophenone.
7. The method for producing the active energy ray-curable inkjet ink cured film according to claim 1 , wherein the initiator further comprises oligo [2-hydroxy-2-methyl-1-{4-(1-methylvinyl)phenyl}propanone].