Process and system for producing liquid biofuel from bio-based oils and/or fats
A process for utilizing bio-based oils and/or fats for producing biofuels includes the steps of: mixing alcohol with a raw material for forming a reaction mixture; pumping the reaction mixture to a reactor; mixing biogas as a catalyst with the reaction mixture in a selected process step either before or after the supply of the reaction mixture to a high-pressure pump, the biogas including methane and carbon dioxide; adjusting a temperature and pressure of the reactor so that the reaction mixture achieves a supercritical state; esterifying the reaction mixture to produce liquid biofuel and by-products; separating the by-products including methane and alcohol from the liquid biofuel; and recovering separated methane. An equivalent system for utilizing bio-based oils and/or fats for producing biofuels is also disclosed.
1. A process for utilizing bio-based oils and/or fats for producing biofuels using a reactor having at least one spiral pipe and a heat transfer tank surrounding said pipe, comprising the steps of:
mixing alcohol with a raw material for forming a reaction mixture,
pumping the reaction mixture to the reactor,
mixing biogas as a catalyst with the reaction mixture in a selected process step either before or after the supply of the reaction mixture to a high-pressure pump, the biogas including methane and carbon dioxide and further including sulfur functioning as a catalyst for an esterification process,
adjusting a temperature and pressure of the reactor so that the reaction mixture achieves a supercritical state,
esterifying the reaction mixture to produce liquid biofuel and by-products,
separating the by-products including methane and alcohol from the liquid biofuel, and
recovering separated methane.
2. A process according to claim 1 , wherein said sulfur is in the form of hydrogen sulfide, said sulfur precipitating reactions and raising an extent of esterification.
3. A process according to claim 1 , wherein the step of mixing the biogas with the reaction mixture includes supplying the biogas under a high pressure into the pressurized reaction mixture before the reactor.
4. A process according to claim 1 , wherein the step of mixing the biogas with the reaction mixture includes feeding the biogas into the reaction mixture before the pumping of the reaction mixture.
5. A process according to claim 3 , wherein the step of recovering separated methane includes recovering methane separated from the biogas before the pumping of the reaction mixture and after carbon dioxide has been absorbed in the reaction mixture.
6. A process according to claim 1 , including the step of using the reactor in continuous operation.
7. A process according to claim 1 , wherein the temperature of the reactor ranges between 70° C. and 500° C.
8. A process according to claim 1 , wherein the temperature of the reactor ranges between 150° C. and 450° C.
9. A process according to claim 1 , wherein the temperature of the reactor ranges between 250° C. and 330° C.
10. A process according to claim 1 , wherein the pressure of the reactor ranges between 50 and 600 bar.
11. A process according to claim 1 , wherein the pressure of the reactor ranges between 140 and 400 bar.
12. A process according to claim 1 , wherein the pressure of the reactor ranges between 160 and 260 bar.
13. A process according to claim 1 , wherein the step of separating biofuel from alcohol and by-products is performed by distillation.
14. A process according of claim 1 , including the step of purifying biofuel by dry washing, wherein biomass is used as an ion exchanger.
15. A process according to claim 1 , wherein the reaction mixture has a uniform flow over an entire range of the reactor.
16. A process according to claim 1 , wherein the biogas is only used as the catalyst and alcohol as a reagent in the reactor.
17. A process according to claim 1 , including the step of recirculating part of the biofuel discharged from the reactor back to the reactor to act as a catalyst.
18. A process according to claim 17 , wherein the portion of the biofuel discharged from the reactor corresponds to less than 30% by volume of a combined volume of the biogas supplied to the reactor.
19. A process according to claim 17 , wherein the portion of the biofuel discharged from the reactor corresponds to less than 10% by volume of a combined volume of the biogas supplied to the reactor.
20. A process according to claim 17 , wherein the portion of the biofuel discharged from the reactor corresponds to less than 5% by volume of a combined volume of the biogas supplied to the reactor.
21. A process according to claim 1 , wherein a ratio of the biogas supplied ranges between 15% and 70% relative to the raw material used.
22. A process according to claim 1 , wherein a ratio of the biogas supplied ranges between 30% and 45% relative to the raw material used.