Rechargeable lithium battery and negative electrode for same
In an aspect, a rechargeable lithium battery that includes a positive electrode including a composite positive active material; a negative electrode including a carbon-based negative active material; an electrolyte including an additive, and a lithium salt and an organic solvent, wherein a passivation film may be on a surface of the negative electrode of the rechargeable lithium battery.
1. A rechargeable lithium battery, comprising:
a positive electrode including a composite positive active material including Chemical Formula 2;
a negative electrode including a carbon-based negative active material; and
an electrolyte including an additive, a lithium salt, and an organic solvent, wherein the additive is:
wherein the additive is included in an amount of about 1 volume % to about 20 volume % based on the total amount, 100 volume %, of the organic solvent,
wherein a passivation film having dots as morphological features of its surface is formed on a surface of the negative electrode after charge and discharge of the rechargeable lithium battery, wherein each dot has a spherical shape having a diameter of 0.2 μm to 2 μm and wherein the dots are present at an area of greater than or equal to about 1% and less than about 20% based on the entire area, 100% of the negative electrode,
wherein the charge and discharge is performed at about 2.0V to about 4.65V, and
wherein the charge and discharge is performed at less than or equal to about 0.5 C:
p Li 2 MnO 3 -(1 −p )LiNi a Co b Mn c O 2 Chemical Formula 2
wherein, in Chemical Formula 2,
0<p<1, 0<a<1, 0<b<1, 0<c<1, and a+b+c=1.
2. The rechargeable lithium battery of claim 1 , wherein the additive is included in an amount of 1 volume % to 20 volume % based on the total amount, 100 volume %, of the organic solvent.
3. The rechargeable lithium battery of claim 1 , wherein the carbon-based negative active material is crystalline carbon.
4. The rechargeable lithium battery of claim 1 , wherein the dots are present at an area of greater than or equal to 1% and less than 20% based on the entire area, 100% of the negative electrode.
5. The rechargeable lithium battery of claim 1 , wherein the charge and discharge is performed at 2.0V to 4.65V.
6. The rechargeable lithium battery of claim 1 , wherein the charge and discharge is performed at less than or equal to 0.5 C.
7. The rechargeable lithium battery of claim 1 , wherein the passivation film includes LiF.
8. The rechargeable lithium battery of claim 1 , wherein the additive is:
9. The rechargeable lithium battery of claim 1 , wherein the additive is: