Strengthened glass with deep depth of compression
Chemically strengthened glass articles having at least one deep compressive layer extending from a surface of the article to a depth of at least about 45 μm within the article are provided. In one embodiment, the compressive stress profile includes a single linear segment extending from the surface to the depth of compression DOC. Alternatively, the compressive stress profile includes two linear portions: the first portion extending from the surface to a relatively shallow depth and having a steep slope; and a second portion extending from the shallow depth to the depth of compression. The strengthened glass has a 60% survival rate when dropped from a height of 80 cm in an inverted ball drop test and an equibiaxial flexural strength of at least 10 kgf as determined by abraded ring-on-ring testing. Methods of achieving such stress profiles are also described.
1. A strengthened glass having a thickness t, the strengthened glass comprising:
an inner region under a central tension CT; and
at least one compressive stress layer under a compressive stress CS, the compressive stress layer extending from a surface of the glass to a depth of compression DOC, wherein DOC≧0.1·t when t<0.5 mm and DOC≧50 μm when t≧0.5 mm, and being adjacent to the inner region,
wherein the strengthened glass has at least a 60% survival rate when subjected to an inverted ball drop test with a 4.2 g stainless steel ball having a diameter of 10 mm from a height of about 80 cm onto a 30 grit sandpaper positioned above the surface of the glass so there is a 100 μm air gap between the sandpaper and the surface of the glass, wherein the survival rate is based on testing at least 5 samples,
wherein the strengthened glass is lithium-free, and
wherein the thickess t is less than or equal to 1 mm.
2. The strengthened glass of claim 1 , wherein a CS at a surface of the glass is in a range from about 500 MPa up to about 1200 MPa and wherein the compressive layer has a compressive stress profile comprising:
a. a first portion b extending from the surface to a depth d b and having a slope m b , wherein 3 μm≦d b ≦15 μm and −40 MPa/μm≧m b ≧−200 MPa/μm;
b. a second portion c extending from a depth d c to the DOC and having an average slope m c wherein −2 MPa/μm≦m c ≦−8 MPa/μm; and
c. a transition region extending from d b to d c having a slope that transitions from slope m b to slope m c .
3. The strengthened glass of claim 2 , wherein −40 MPa/μm≧m b ≧−120 MPa/μm.
4. The strengthened glass of claim 2 , wherein the first portion b is is linear such that
σ
″
(
x
)
<
2
σ
′
(
ω
)
d
b
where σ″(x) is the second derivative of the stress profile in the first portion b with respect to depth x and σ′(x) is the first derivative of the stress profile in the first portion b with respect to depth x.
5. The strengthened glass of claim 2 , wherein the second portion c is is linear such that
σ
″
(
x
)
<
2
σ
′
(
x
)
d
c
where σ″(x) is the second derivative of the stress profile in the second portion c with respect to depth x and σ′(x) is the first derivative of the stress profile in the second portion c with respect to depth x.
6. The strengthened glass of claim 1 , wherein the thickness t is in a range from about 0.15 mm up to 1 mm.
7. The strengthened glass of claim 1 , wherein the strengthened glass comprises an alkali aluminosilicate glass.
8. The strengthened glass of claim 7 , wherein the alkali aluminosilicate glass comprises at least about 4 mol % P 2 O 5 and from 0 mol % to about 4 mol % B 2 O 3 , wherein 1.3<[(P 2 O 5 +R 2 O)/M 2 O 3 ]≦2.3, where M 2 O 3 =Al 2 O 3 +B 2 O 3 , and R 2 O is the sum of monovalent cation oxides present in the alkali aluminosilicate glass.
9. The strengthened glass of claim 1 , wherein the strengthened glass that has had a surface sandblasted with abrasive material at a load of 15 psi for 5 seconds has a peak load at a failure in a range from about 10 kgf to about 50 kgf as determined by abraded ring-on-ring testing wherein a ratio of a diameter of a loading ring D 1 to a diameter of a support ring D 2 is about 0.5.
10. An electronic device comprising the strengthened glass of claim 1 .