IP Library Granted Patent US 9,905,361
Granted Patent B2
US 9,905,361 · App. 14/430,463 · Granted Feb 27, 2018

Manufacturing method of common grain-oriented silicon steel with high magnetic induction

Inventors: Kanyi Shen (Shanghai, CN); Guobao Li (Shanghai, CN); Shuangjie Chu (Shanghai, CN); Yezhong Sun (Shanghai, CN); Huabing Zhang (Shanghai, CN); Yongjie Yang (Shanghai, CN); Zhuochao Hu (Shanghai, CN); Bin Zhao (Shanghai, CN); Qi Xu (Shanghai, CN); Jie Huang (Shanghai, CN); Peili Zhang (Shanghai, CN)
Assignee: Baoshan Iron & Steel Co., Ltd.
H01F41/02C21D3/04C21D6/008C21D8/12C21D8/1205C21D8/1222C21D8/1233C21D8/1261C21D8/1272C21D8/1277C21D8/1283C22C38/001C22C38/008C22C38/02C22C38/04C22C38/06C23C8/26H01F1/14783H01F1/14791H01F1/18H01F41/32C21D2201/05
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Quick Facts
Patent No.
US 9,905,361
App. No.
14/430,463
Granted
Feb 27, 2018
Kind
B2
Abstract

A manufacturing method of oriented silicon steel with magnetic induction B8 of not less than 1.88 T, comprising the following steps: 1) smelting and continuous casting to obtain a slab, wherein the content of N is controlled at 0.002-0.014 wt % in the smelting stage; 2) hot-rolling; 3) cold-rolling; 4) decarbonizing and annealing; 5) nitriding treatment, wherein infiltrated nitrogen content [N] D is controlled to satisfy the formula: 328−0.14a−0.85b−2.33c≦[N] D ≦362−0.16a−0.94b−2.57c, wherein a is the content of Als in the smelting step, with the unit of ppm; b is the content of N element, with the unit of ppm; and c is primary grains size, with the unit of μm; 6) coating a steel's surfaces with a magnesium oxide layer and annealing; and 7) applying an insulating coating.

Claims (13)

1. A manufacturing method of common oriented silicon steel having high magnetic induction, comprising the following steps:

(1) smelting and continuous casting to obtain a slab, wherein the content of N is controlled in a range of 0.002-0.014 wt % in the smelting stage;

(2) hot-rolling, wherein a heating temperature is 1090-1200° C.;

(3) cold-rolling, wherein a primary aging-free rolling is performed;

(4) decarbonizing and annealing;

(5) nitriding treatment, wherein infiltrated nitrogen content [N] D satisfies the following formula: 328−0.14a−0.85b−2.33c≦[N] D ≦362−0.16a−0.94b−2.57c, wherein a is the content of Als in the smelting step, with a unit of ppm; b is the content of N element in the smelting step, with a unit of ppm; and c is the size of primary grains, with a unit of μm;

(6) coating a magnesium oxide layer on a steel plate's surfaces, and annealing; and

(7) coating an insulation layer.

2. The manufacturing method of common oriented silicon steel having high magnetic induction according to claim 1 , wherein in the step (2), the hot-rolling begins at a temperature of 1180° C. or below, and ends at a temperature of 860° C. or above, and then a coiling after the hot-rolling is performed at a temperature of below 650° C.

3. The manufacturing method of common oriented silicon steel having high magnetic induction according to claim 2 , wherein in said step (3), a cold-rolling reduction ratio is not less than 80%.

4. The manufacturing method of common oriented silicon steel having high magnetic induction according to claim 3 , wherein in the step (4), a heating rate is 15-35° C./s, a decarbonizing temperature is 800-860° C., and a decarbonizing dew point is 60-70° C.

5. The manufacturing method of common oriented silicon steel having high magnetic induction according to claim 4 , wherein in the step (4), a protective atmosphere is 75% H 2 +25% N 2 .

6. The manufacturing method of common oriented silicon steel having high magnetic induction according to claim 1 , wherein in the step (5), the nitriding is performed by NH 3 with a volume fraction of 0.5-4.0%, at a temperature of 760-860° C., within a time of 20-50 s, and in an oxidation degree P H2O /P H2 of 0.045-0.200.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2015
From: SHEN, KANYI; LI, GUOBAO; CHU, SHUANGJIE; SUN, YEZHONG; ZHANG, HUABING; YANG, YONGJIE; HU, ZHUOCHAO; ZHAO, BIN; XU, QI; HUANG, JIE; ZHANG, PEILI
To: BAOSHAN IRON & STEEL CO., LTD.
Reel/Frame 035233/0924 →
Priority Claims (1)
CN 2012 1 0365931 · Sep 27, 2012 · national
Continuity (1)
Related Publication 20150255211A1 · Sep 10, 2015