Alkylamine-gold nanoparticles having tunable electrical and optical properties
View Patent ↗Disclosed herein are monolayers comprising alkylamine-gold nanoparticles that have tunable electrical and optical properties. Also disclosed is a method for forming the monolayers that comprises self-assembly of the nanoparticles.
1. A nanoparticle monolayer having tunable optical and electrical properties, comprising alkylamine-gold nanoparticles having an interparticle spacing from about 0.5 nm to about 5 nm.
2. The monolayer according to claim 1 , wherein the alkylamine is chosen from C 6 -C 18 linear or branched, saturated or unsaturated alkylamines.
3. The monolayer according to claim 1 , wherein the alkylamine is a polystyrene amine.
4. The monolayer according to claim 1 , wherein the alkylamine-gold nanoparticle monolayer has an interparticle spacing of from about 0.5 nm to about 4 nm.
5. The monolayer according to claim 1 , wherein the alkylamine-gold nanoparticle monolayer has an interparticle spacing of from about 1 nm to about 4 nm.
6. The monolayer according to claim 1 , wherein the alkylamine-gold nanoparticle monolayer has an interparticle spacing of from about 1 nm to about 3 nm.
7. The monolayer according to claim 1 , wherein the gold nanoparticles have an average diameter of from about 1 nm to about 100 nm.
8. The monolayer according to claim 1 , wherein the gold nanoparticles have an average diameter of from about 5 nm to about 40 nm.
9. A method for preparing an alkylamine-gold nanoparticle monolayer, comprising:
a) charging to a vessel a first organic solution of an alkylamine;
b) injecting an aqueous colloid of gold nanoparticles below the surface of the organic solution in an amount sufficient to allow the colloid to protrude through the organic solution and form an organic solution/water and water/air interface; and
c) adding to the organic solution/water interface a second organic solution in sufficient amount to cause the gold nanoparticles to propagate to the water/air interface.
10. The method according to claim 9 , wherein the alkylamine is chosen from C 6 -C 18 linear or branched, saturated or unsaturated alkylamines.
11. The method according to claim 9 , wherein the alkylamine is a polystyrene amine.
12. The method according to claim 9 , wherein the alkylamine-gold nanoparticle monolayer has an interparticle spacing of from about 0.5 nm to about 5 nm.
13. The method according to claim 9 , wherein the alkylamine-gold nanoparticle monolayer has an interparticle spacing of from about 1 nm to about 3 nm.
14. The method according to claim 9 , wherein the alkylamine is dodecylamine.
15. The method according to claim 9 , wherein the alkylamine is pentadecylamine.
16. The method according to claim 9 , wherein the alkylamine is octadecylamine.
17. The method according to claim 9 , wherein the alkylamine is oleylamine.
18. The method according to claim 9 , wherein the aqueous colloid further comprises a charge stabilizer.
19. The method according to claim 9 , wherein the first organic solution contains hexane, chloroform or mixtures thereof.
20. The method according to claim 9 , wherein the second organic solution is ethanol.