Flexible display device and manufacturing method thereof
Disclosed herein is a flexible display device, including: a substrate that comprises a first surface and a second surface which is an opposite surface to the first surface; a light-emitting device disposed on the first surface; a reduction layer disposed on the second surface; and a barrier layer disposed between the second surface and the reduction layer.
1. A manufacturing method for a flexible display device, comprising:
forming a release layer on a support substrate;
forming a barrier layer on the release layer;
forming a substrate and a light-emitting device on the barrier layer;
forming a reduction layer by reducing a portion of the release layer adjacent to the barrier layer by performing a first heat treatment;
separating the substrate from the support substrate by separating an interface between the release layer and the reduction layer; and
wherein the release layer comprises a metal oxide.
2. The manufacturing method for the flexible display device of claim 1 , wherein the first heat treatment is performed at about from 400° C. to about 500° C. for from about 0.5 to about 4 h.
3. The manufacturing method for the flexible display device of claim 1 , wherein the reduction layer has a smaller coefficient of thermal expansion (CTE) than the release layer.
4. The manufacturing method for the flexible display device of claim 1 , wherein the release layer has a thickness of from about 500 Å to about 2000 Å.
5. The manufacturing method for the flexible display device of claim 1 , wherein the release layer comprises at least one of molybdenum trioxide MoO 3 and manganese dioxide (MnO 2 ).
6. The manufacturing method for the flexible display device of claim 5 , wherein the forming of the release layer comprises depositing molybdenum (Mo) or manganese (Mn) by sputtering and then performing a second heat treatment for the deposited molybdenum (Mo) or manganese (Mn) in an air atmosphere including oxygen.
7. The manufacturing method for the flexible display device of claim 6 , wherein the second heat treatment is performed at from about 400° C. to about 450° C.
8. The manufacturing method for the flexible display device of claim 1 , wherein the barrier layer comprises hydrogen.
9. The manufacturing method for the flexible display device of claim 7 , wherein some of the release layer is reduced by the hydrogen included in the barrier layer.
10. The manufacturing method for the flexible display device of claim 7 , wherein the forming of the barrier layer comprises depositing at least one of silicon (Si), silicon oxide (SiOx), silicon nitride (SiNx), and silicon oxynitride (SiON) while supplying hydrogen gas as one of reaction gasses.