Method for concentrating aqueous containing solute into high concentration by hydraulic-membrane process under no difference in osmotic pressure
The present invention relates to a method of concentrating an aqueous solution at low pressure under a zero osmotic pressure difference condition, and more particularly, to a method of concentrating an aqueous solution containing a solute to be concentrated, at low pressure under a zero osmotic pressure difference condition. The method of the present invention comprises the steps of: (a) discharging water of a solute-containing aqueous solution to be concentrated, from a reverse osmosis separator to the outside, and transferring the concentrated aqueous solution to a zero osmotic pressure difference concentrator; (b) further concentrating the concentrated aqueous solution using the zero osmotic pressure difference concentrator comprising a feed chamber and a draw chamber, which are separated from each other by a reverse osmosis membrane or a forward osmosis membrane; and (c) recovering the solute and water from the aqueous solution further concentrated in the zero osmotic pressure difference concentrator. When the method of concentrating the aqueous solution at low pressure under the zero osmotic pressure difference condition is used, the aqueous solution can be concentrated to the maximum saturation concentration of a solute or a solution concentration of 100% using a reduced amount of energy without having to use an extraction solvent. In addition, there is an advantage in that a separate osmosis draw solution does not need to be used.
1. A method of concentrating an aqueous solution containing a solute to be concentrated, the method comprising the steps of:
(a) firstly concentrating, by reverse osmosis, the aqueous solution containing a solute to be concentrated, thereby producing a firstly concentrated solute-containing aqueous solution;
(b) introducing the firstly concentrated solute-containing aqueous solution of step (a) into a zero osmotic pressure difference concentrator comprising a feed chamber and a draw chamber, which are separated from each other by a reverse osmosis membrane, thereby secondly concentrating the introduced solute-containing aqueous solution in the concentrator to produce a secondly concentrated solute-containing aqueous solution; and
(c) recovering the secondly concentrated solute-containing aqueous solution, while recycling a portion of the secondly concentrated solute-containing aqueous solution to the draw chamber to form a zero osmotic pressure difference between the feed chamber and the draw chamber,
wherein step (b) comprises the steps of:
(i) transferring the firstly concentrated aqueous solution of step (a) to the feed chamber of the zero osmotic pressure difference concentrator, and introducing into the draw chamber the aqueous solution transferred to the feed chamber having an osmotic pressure identical to that of the aqueous solution transferred to the feed chamber, thereby forming the zero osmotic pressure difference between the feed chamber and the draw chamber; and
(ii) applying a pressure for the reverse osmosis membrane to the feed chamber under the zero osmotic pressure difference condition to transfer water of the concentrated aqueous solution to the draw chamber, thereby further concentrating the concentrated aqueous solution; and
wherein step (c) comprises the steps of:
(i) transferring 10 wt %-90 wt % of the secondly concentrated solute-containing aqueous solution to the draw chamber to maintain the osmotic pressure of the draw chamber equal to that of the feed chamber;
(ii) transferring solute-containing aqueous solution from the draw chamber to a reverse osmosis separator to produce a thirdly concentrated solute-containing aqueous solution, and discharging water of the solute-containing aqueous solution to outside; and
(iii) transferring the thirdly concentrated solute-containing aqueous solution to the zero osmotic pressure difference concentrator.
2. The method of claim 1 , wherein the aqueous solution containing a solute to be concentrated is selected from the group consisting of seawater, brackish water, aqueous solutions of cellular metabolites, and aqueous solutions of reaction products.
3. The method of claim 1 , wherein the volume ratio of the draw chamber to the feed chamber of the zero osmotic pressure difference concentrator is 1/10 to 1/100.
4. The method of claim 1 , wherein the concentration by the zero osmotic pressure difference concentrator in step (b) is performed in a batch manner or a continuous manner.
5. The method of claim 1 , wherein each of the feed chamber and the draw chamber is composed of multiple stages.
6. The method of claim 1 , wherein the aqueous solution containing a solute has a pH of 2-13 and a temperature at which water is maintained in liquid state.
7. The method of claim 1 , wherein recovery of the solute and water from the aqueous solution concentrated in the zero osmotic pressure difference concentrator is performed by a method selected from the group consisting of a multi-stage flash process, a pervaporation process, a thermal decomposition process, a sulfuric acid process, and a calcium process.