IP Library › Granted Patent US 9,951,290
Granted Patent B2
US 9,951,290 · App. 15/086,892 · Granted Apr 24, 2018

Lubricant compositions

Inventors: Jason Z. Gao (Rose Valley, PA); Samuel C. Bainbridge (Philadelphia, PA); Luca Salvi (Philadelphia, PA)
Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
C10M141/10C10M139/00C10M141/12C10M2207/28C10M2207/2805C10M2215/223C10M2219/066C10M2219/106C10M2223/045C10M2227/061C10N2210/06C10N2230/06C10N2230/12C10N2230/40C10N2230/42C10N2230/54C10N2240/10C10N2260/14
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Quick Facts
Patent No.
US 9,951,290
App. No.
15/086,892
Granted
Apr 24, 2018
Kind
B2
Abstract

A method for improving corrosion protection and friction coefficient in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition comprising a lubricating oil base stock as a major component, and a mixture of (i) at least one organic molybdenum compound, and (ii) at least one borated ester, as a minor component. Corrosion protection and friction coefficient are improved as compared to corrosion protection and friction coefficient achieved using a lubricating oil containing a minor component other than the mixture of (i) at least one organic molybdenum compound, and (ii) at least one borated ester.

Claims (12)

1. A method for improving corrosion protection and friction coefficient in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil, said formulated oil having a composition comprising a lubricating oil base stock comprising a monoester and other synthetic base oil; a viscosity modifier; and a mixture of (i) at least one molybdenum dithiophosphate having a molybdenum to sulfur ratio of about 0.93, and (ii) at least one borated ester, as a minor component; wherein corrosion protection and friction coefficient are improved as compared to corrosion protection and friction coefficient achieved using a lubricating oil containing a minor component other than the mixture of (i) at least one molybdenum dithiophosphate having a molybdenum to sulfur ratio of about 0.93, and (ii) at least one borated ester,

wherein the monoester comprises about 20 wt. % of the formulated oil, the combination of the other synthetic base oil and viscosity modifier comprise from about 66.47 to 69.037 wt. % of the formulated oil, the at least one molybdenum dithiophosphate having a molybdenum to sulfur ratio of about 0.93 comprises from 0.763 to 1.526 wt. % of the formulated oil, and the at least one borated ester represented by the following formula:

as well as unreacted glycerol, glycerol mono-, di- and tri-ester,

unreacted

unreacted boronating agent and unboronated

and comprises from about 0.4 to 1.0 wt. % of the formulated oil, and wherein the formulated oil has a friction coefficient of 0.04 or lower at 140° C., as measured by the Mini Traction Machine (MTM) under a contact pressure of 1.0 GHz, and a copper strip rating of 1A or 1B as measured by ASTM D130 at 150° C.

2. A lubricating oil having a composition comprising a lubricating oil base stock comprising a monoester and other synthetic base oil; a viscosity modifier; and a mixture of (i) at least one molybdenum dithiophosphate having a molybdenum to sulfur ratio of about 0.93, and (ii) at least one borated ester, as a minor component; wherein corrosion protection and friction coefficient are improved as compared to corrosion protection and friction coefficient achieved using a lubricating oil containing a minor component other than the mixture of (i) at least one molybdenum dithiophosphate having a molybdenum to sulfur ratio of about 0.93, and (ii) at least one borated ester,

wherein the monoester comprises about 20 wt. % of the formulated oil, the combination of the other synthetic base oil and viscosity modifier comprise from about 66.47 to 69.037 wt. % of the formulated oil, the at least one molybdenum dithiophosphate having a molybdenum to sulfur ratio of about 0.93 comprises from 0.763 to 1.526 wt. % of the formulated oil, and the at least one borated ester is represented by the following formula:

as well as unreacted glycerol, glycerol mono-, di- and tri-ester,

unreacted

unreacted boronating agent and unboronated

and comprises from about 0.4 to 1.0 wt. % of the formulated oil, and wherein the formulated oil has a friction coefficient of 0.04 or lower at 140° C., as measured by the Mini Traction Machine (MTM) under a contact pressure of 1.0 GHz, and a copper strip rating of 1A or 1B as measured by ASTM D130 at 150° C.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 13, 2016
From: GAO, JASON Z.; BAINBRIDGE, SAMUEL C.; SALVI, LUCA
To: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Reel/Frame 039148/0307 →
Continuity (1)
Related Publication 20170283731A1 · Oct 5, 2017