Three dimensional secondary battery including elastic member and method of fabricating the same
A three dimensional (“3D”) secondary battery includes an electrolyte layer and an anode active material layer that are sequentially stacked on a plurality of first trenches that are provided in a cathode active material layer where, in the anode active material layer, a plurality of second trenches having similar shape to that of the first trenches is provided and the plurality of second trenches are filled with an elastic member and where the elastic member absorbs expansion of the anode active material layer during charging and discharging the 3D secondary battery, and thus, the degradation of the 3-dimensional secondary battery is prevented.
1. A three dimensional secondary battery comprising:
a cathode collector;
a cathode active material layer on an upper surface of the cathode collector, the cathode active material layer including a plurality of first trenches on an upper surface thereof;
an electrolyte layer covering the upper surface of the cathode active material layer and an exposed surface of the cathode active material layer by the plurality of first trenches;
an anode active material layer on the electrolyte layer, the anode active material layer including a plurality of second trenches corresponding to the plurality of first trenches;
a plurality of elastic members including at least one of a polymer and a rubber, each filling respective one of the plurality of second trenches; and
an anode collector covering the anode active material layer and the plurality of elastic members.
2. The three dimensional secondary battery of claim 1 , wherein each of the plurality of elastic members includes at least one of styrene-butadiene rubber (“SBR”), butadiene rubber (“BR”), isoprene rubber (“IR”), ethylene propylene diene monomer (“EPDM”) rubber, silicone rubber, alkyl acrylate copolymer (“ACM”), styrene-butadiene copolymer (“SBS”), styrene-ethylene-butadiene-styrene copolymer (“SEBS”), polymethylsilane rubber, and butyl acrylate copolymer.
3. The three dimensional secondary battery of claim 2 , wherein each of the plurality of elastic members includes a conduction agent.
4. The three dimensional secondary battery of claim 3 , wherein the conduction agent includes at least one of carbon black and carbon nanotubes.
5. The three dimensional secondary battery of claim 1 , wherein the anode active material layer includes at least one of lithium metal, silicon, tin, aluminum, and germanium.
6. The three dimensional secondary battery of claim 1 , wherein the cathode active material layer further comprises:
a plurality of third trenches on a surface facing the cathode collector; and
a plurality of second elastic members that fill respective one of the plurality of third trenches.
7. The three dimensional secondary battery of claim 6 , wherein the plurality of first trenches and the plurality of third trenches are alternately provided and are parallel to each other when viewed from a plan view.
8. A three dimensional secondary battery comprising:
a cathode collector;
a plurality of cathode active material plates disposed perpendicular to the cathode collector;
an electrolyte layer on the cathode collector to cover the plurality of cathode active material plates;
a plurality of anode active material layer, each covering the electrolyte layer between adjacent cathode active material plates to form corresponding one of a plurality of first trenches;
a plurality of elastic members including at least one of a polymer and a rubber, each filling respective one of the plurality of first trenches; and
an anode collector that covers the anode active material layer and the plurality of elastic members.
9. The three dimensional secondary battery of claim 8 , wherein each of the plurality of elastic members includes at least one of styrene-butadiene rubber (“SBR”), butadiene rubber (“BR”), isoprene rubber (“IR”), ethylene propylene diene monomer (“EPDM”) rubber, silicone rubber, alkyl acrylate copolymer (“ACM”), styrene-butadiene copolymer (“SBS”), styrene-ethylene-butadiene-styrene copolymer (“SEBS”), polymethylsilane rubber, and butyl acrylate copolymer.
10. The three dimensional secondary battery of claim 9 , wherein each of the plurality of elastic members includes a conduction agent.
11. The three dimensional secondary battery of claim 10 , wherein the conduction agent includes at least one of carbon black and carbon nanotubes.
12. The three dimensional secondary battery of claim 8 , wherein the anode active material layer includes at least one of lithium metal, silicon, tin, aluminum, and germanium.
13. The three dimensional secondary battery of claim 8 , wherein the cathode active material plates further comprise:
a plurality of second trenches disposed on a surface facing the cathode collector; and
a plurality of second elastic members, each filling respective one of the plurality of second trenches.
14. The three dimensional secondary battery of claim 13 , wherein a plurality of third trenches is defined in the cathode active material layer, and
wherein the plurality of first trenches and the plurality of third trenches are alternately provided and are parallel to each other when viewed from a plan view.
15. A method of manufacturing a three dimensional secondary battery, the method comprising:
preparing a cathode collector;
forming a cathode active material layer on the cathode collector;
forming a plurality of first trenches on an upper surface of the cathode active material layer;
sequentially forming an electrolyte layer and an anode active material layer in the plurality of first trenches and on the cathode active material layer to form a plurality of second trenches in the anode active material layer, each of the plurality of second trenches corresponding to respective one of the plurality of first trenches;
filling each of the plurality of second trenches with respective one of the plurality of elastic members including at least one of a polymer and a rubber; and
forming an anode collector on the anode active material layer to cover the plurality of elastic members.
16. The method of claim 15 , wherein the filling each of the plurality of second trenches with the elastic member comprises:
filling each of the plurality of second trenches with a monomer; and
polymerizing the monomer.
17. The method of claim 16 , wherein the filling each of the plurality of second trenches with the monomer further comprises adding at least one of an initiator, a catalyst, and a radical to the monomer.
18. The method of claim 16 , wherein the filling each of the plurality of second trenches with the monomer further comprises adding a conduction agent to the monomer.
19. The method of claim 15 , wherein the elastic member includes at least one of styrene-butadiene rubber (“SBR”), butadiene rubber (“BR”), isoprene rubber (“IR”), ethylene propylene diene monomer (“EPDM”) rubber, silicone rubber, alkyl acrylate copolymer (“ACM”), styrene-butadiene copolymer (“SBS”), styrene-ethylene-butadiene-styrene copolymer (“SEBS”), polymethylsilane rubber, and butyl acrylate copolymer.
20. The method of claim 15 , wherein the anode active material layer includes at least one of lithium metal, silicon, tin, aluminum, and germanium.