IP Library Granted Patent US 9,982,133
Granted Patent B2
US 9,982,133 · App. 14/906,325 · Granted May 29, 2018

Polyamide composition

Inventors: Stéphane Jeol (Cumming, GA); Thierry Badel (Lyons, FR)
Assignee: Rhodia Operations
C08L77/12C08L77/00C08K5/053C08K7/14C08L51/06C08L2201/08C08L2205/06
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Quick Facts
Patent No.
US 9,982,133
App. No.
14/906,325
Granted
May 29, 2018
Kind
B2
Abstract

The invention pertains to a filled polyamide composition [composition (C)] comprising: —from 35 to 80% wt of at least one polyhydric alcohol-modified polyamide, comprising an amount of polyhydric alcohol (PHA, herein after) residues chemically bonded at least to a part of the polyamide [polyamide (A)] of at least 0.1% wt (based on the total weight of polyamide (A)); —from 10 to 65% wt of at least one filler [filler (F)]; —from 1 to 10% wt of at least one impact modifying rubber [rubber (I)]; and —from 0.01 to 3% wt of at least one copper-containing stabilizer, with above % wt being referred to the total weight of composition (C).

Claims (17)

1. A filled polyamide composition comprising, based on the total weight of the composition:

from 50 to 70% wt of at least one polyhydric alcohol-modified polyamide, said polyhydric alcohol-modified polyamide comprising an amount of at least 0.1% wt and at most 10% wt, based on the total weight of the polyhydric alcohol-modified polyamide, of polyhydric alcohol residues chemically bonded at least to a part of the polyhydric alcohol-modified polyamide, wherein said polyhydric alcohol is an organic compound containing three or more hydroxyl groups in the molecule and is selected from dipentaerythritol and tripentaerythritol;

from 15 to 50% wt of at least one filler comprising glass fibers;

from 3 to 6% wt of at least one impact modifying rubber comprising ethylene amorphous copolymers grafted with maleic anhydride; and

from 0.01 to 3% wt of at least one copper-containing stabilizer, wherein the copper-containing stabilizer provides 75 to 150 ppm copper to the filled polyamide composition, wherein the polyamide is polyamide 6,6.

2. The composition of claim 1 , wherein the polyhydric alcohol-modified polyamide is obtained by condensation reaction in the presence of the at least one polyhydric alcohol, of a monomer mixture of adipic acid and 1,6-diaminohexane; wherein the amount of polyhydric alcohol used in the condensation reaction is from 0.15 to 20% wt, based on the total weight of the at least one monomer mixture.

3. The composition of claim 1 , wherein the polyhydric alcohol-modified polyamide has a content of chemically bonded polyhydric alcohol residues of at least 0.5% wt, and at most 10% wt, based on the total weight of the polyhydric alcohol-modified polyamide.

4. The composition of claim 1 , wherein the polyhydric alcohol-modified polyamide comprises non-chemically bonded polyhydric alcohol in an amount of less than 2% wt, based on the total weight of the polyhydric alcohol-modified polyamide.

5. The composition of claim 1 , wherein the copper-containing stabilizer comprises a copper compound and an alkali metal halide in a weight ratio of copper compound:alkali metal halide of from 1:99 to 30:70.

6. The composition of claim 1 , further comprising a co-stabilizer selected from the group consisting of hindered amine compounds, hindered phenol compounds, and phosphorous compounds.

7. A method of making the composition according to claim 1 , said method comprising melt-blending the polyhydric alcohol-modified polyamide, the filler, the rubber, the copper-containing stabilizer, and of any other optional ingredient.

8. A method for manufacturing an article, comprising shaping the composition of claim 1 by a shaping technique selected from the group consisting of extrusion, injection moulding, thermoform moulding, compression moulding and blow moulding.

9. The method according to claim 8 , wherein the article is selected from the group consisting of films, laminates, automotive parts, engine parts, electrical parts, and electronics parts.

10. The method according to claim 8 , wherein the article is suitable for high temperature applications.

11. The composition of claim 3 , wherein the polyhydric alcohol-modified polyamide comprises from 0.75% wt to 7% wt chemically bonded polyhydric alcohol residues, based on the total weight of the polyhydric alcohol-modified polyamide.

12. The composition of claim 4 , wherein the polyhydric alcohol-modified polyamide comprises less than 1.5% wt non-chemically bonded polyhydric alcohol, based on the total weight of the polyhydric alcohol-modified polyamide.

13. The composition claim 5 , wherein the weight ratio of copper compound:alkali metal halide is from 5:95 to 20:80.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 31, 2020
From: RHODIA OPERATIONS
To: PERFORMANCE POLYAMIDES, SAS
Reel/Frame 051686/0612 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2018
From: BADEL, THIERRY
To: RHODIA OPERATIONS
Reel/Frame 045768/0692 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 5, 2016
From: JEOL, STEPHANE
To: RHODIA OPERATIONS
Reel/Frame 038478/0773 →
Priority Claims (1)
EP 13306061 · Jul 23, 2013 · regional
Continuity (1)
Related Publication 20160177094A1 · Jun 23, 2016