Method for producing finely structured surfaces
A method for producing finely structured surfaces, in particular in plastics, includes a) applying at least one coating compound on at least one substrate; b) forming a fine structure by a die, which has the negative of a fine structure, c) curing the resultant finely structured coating compound, obtaining a substantially cured coating; and d) separating the finely structured coating from the die, wherein steps d) and c) can also be carried out in the reverse order.
1. A method for producing finely structured coated surfaces with an aspect ratio of at least 0.5 for influencing adhesion comprising:
a) applying at least one coating compound on at least one substrate, wherein the at least one coating compound comprises a radiation-curing coating compound having a double bond density of not more than 7 mol/kg, said radiation-curing coating compound comprising a polyester-, polyether-, carbonate-, epoxy- or urethane(meth)acrylate; or an unsaturated polyester resin;
b) forming a fine structure by a die, which has a negative of the fine structure, wherein
b1) the die is pressed against the coating compound on the substrate or
b2) the substrate from step a) contains the die;
c) curing the resultant finely structured coating compound, obtaining a substantially cured coating;
d) separating the finely structured coating from the die, wherein steps d) and c) can also be carried out in any order, and
wherein the coating compound, in a solvent-free state before application on the substrate, has a viscosity below 10 Pa·s, and
wherein the cured coating has an elastic modulus of at least 1 and up to 100 MPa.
2. The method as claimed in claim 1 , wherein the radiation-curing coating compounds comprise polyester-, polyether-, carbonate-, epoxy- or urethane(meth)acrylates, which are partially amine-modified.
3. The method as claimed in claim 1 , wherein the radiation-curing coating compound comprises
at least one polyester-, polyether-, carbonate-, epoxy- or urethane(meth)acrylate or unsaturated polyester resin,
optionally at least one reactive thinner,
optionally at least one photoinitiator,
optionally at least one solvent,
optionally at least one stabilizer, and
optionally at least one additive, selected from the group consisting of activators, fillers, pigments, dyes, thickeners, thixotropic agents, surfactants, viscosity modifiers, plasticizers and chelating agents.
4. The method as claimed in claim 1 , wherein the substrate is selected from the group consisting of polyethylene terephthalate, polypropylene, polyethylene and polymethyl methacrylate.
5. The method as claimed in claim 1 , wherein the die is a die with a hierarchic fine structure.
6. A method for producing finely structured coated surfaces according to claim 1 , wherein the surface has projections and/or depressions with at least one dimension in a range of 100 nm to 750 μm.
7. A method for producing finely structured coated surfaces according to claim 1 , wherein the at least one coating compound comprises a radiation-curing coating compound having a double bond density of at least 0.1 mol/kg.
8. The method as claimed in claim 1 , wherein the coating compound, in a solvent-free state before application on the substrate, has a viscosity below 1 Pa·s.
9. The method as claimed in claim 1 , wherein the radiation-curing coating compound has a double bond density of 4.8 to 7 mol/kg.
10. The method as claimed in claim 1 , wherein the radiation-curing coating compound comprises polyester(meth)acrylates that are esters of α,β-ethylenically unsaturated carboxylic acids with polyester polyols.
11. The method as claimed in claim 1 , wherein the radiation-curing coating compound comprises polyether(meth)acrylates that are the esters of acrylic acid with polyetherols.
12. The method as claimed in claim 1 , wherein the cured coating has an elastic modulus of 2 to 20 MPa.
13. The method as claimed in claim 1 , wherein the coating compound, in a solvent-free state before application on the substrate, has a viscosity of 10 mPa·s to 600 mPa·s.
14. The method as claimed in claim 1 , wherein the radiation-curing coating compound comprises carbonate- or urethane(meth)acrylates; or unsaturated polyester resins.
15. A method according to claim 1 , wherein the surface has projections and/or depressions with at least one dimension in a range of 250 μm to 750 μm.
16. The method as claimed in claim 1 , wherein said radiation-curing coating compound comprising a polyester-, carbonate-, epoxy- or urethane(meth)acrylate; or an unsaturated polyester resin.
17. The method as claimed in claim 1 , wherein the substrate is selected from the group consisting of polypropylene, polyethylene, and polymethyl methacrylate.