Multilayer film and interlayer film for laminated glass therefrom
There is provided a multilayer film comprising a layer (X) containing a polyvinyl acetal (I) having an acetalization degree of 55 to 80 mol %, a content of a vinyl ester monomer unit of 0.1 to 1.5 mol % and a viscosity-average degree of polymerization of 1,400 to 5,000; and a layer (Y) containing a polyvinyl acetal (II) having an acetalization degree of 70 to 85 mol %, a content of a vinyl ester monomer unit of 5 to 15 mol % and a viscosity-average degree of polymerization of 1,400 to 5,000, wherein the multilayer film satisfies formulas (1) and (2): (A−B)/A<0.80 (1) and 1.00×10 −2 <(b/y)/(a/x)<2.00×10 −1 (2). There is thus provided a film which exhibits sufficient sound-absorbability, resistance to coloration by heating, reduction in foreign materials (undissolved materials) and excellent recyclability.
1. A multilayer film, comprising
a layer (X) comprising a polyvinyl acetal (I) having an acetalization degree of 55 to 80 mol %, a content of a vinyl ester monomer unit of 0.1 to 1.5 mol% and a viscosity-average degree of polymerization of 1,400 to 5,000; and
a layer (Y) comprising a polyvinyl acetal (II) having an acetalization degree of 70 to 85 mol %, a content of a vinyl ester monomer unit of 5 to 15 mol % and a viscosity-average degree of polymerization of 1,400 to 5,000,
wherein the multilayer film satisfies formulas (1) and (2):
( A−B )/ A <0.80 (1)
1.00×10 −2 <( b/y )/( a/x )<2.00×10 −1 (2)
wherein
“A” is a peak-top molecular weight of a polymer component as measured by a differential refractive index detector in gel-permeation chromatographic measurement of said multilayer film heated at 230° C. for 3 hours;
“a” is a signal strength at the peak-top molecular weight (A);
“B” is a peak-top molecular weight of a polymer component as measured by an absorptiometer at a measuring wavelength of 280 nm in gel-permeation chromatographic measurement of said multilayer film heated at 230° C. for 3 hours;
“b” is a signal strength at the peak-top molecular weight (B);
“x” is a signal strength at a peak-top molecular weight as measured by a differential refractive index detector in gel-permeation chromatographic measurement of a monodisperse polymethyl methacrylate; and
“y” is a signal strength at a peak-top molecular weight as measured by an absorptiometer at a measuring wavelength of 220 nm in gel-permeation chromatographic measurement of said monodisperse polymethyl methacrylate.
2. The multilayer film according to claim 1 , which further satisfies formulas (3) and (4):
( A−C )/ A <0.80 (3)
5.00×10 −3 <( c/y )/( a/x )<7.00×10 −2 (4)
wherein
“A” is as defined in the formula (1);
“a”, “x” and “y” are as defined in the formula (2);
“C” is a peak-top molecular weight of a polymer component as measured by an absorptiometer at a measuring wavelength of 320 nm in gel-permeation chromatographic measurement of said multilayer film heated at 230° C. for 3 hours; and
“c” is a signal strength at the peak-top molecular weight (C).
3. The multilayer film according to claim 1 , wherein the polyvinyl acetal (I) and the polyvinyl acetal (II) are polyvinyl butyrals.
4. An interlayer film for a laminated glass, consisting of the multilayer film according to claim 1 .
5. A laminated glass, consisting of a plurality of glass sheets bonded via the interlayer film according to claim 4 .
6. A method for producing a monolayer film, the method comprising:
melt-kneading a recovery of the multilayer film according to claim 1 to obtain a melt-kneaded product and
then forming a film from the melt-kneaded product.
7. The method according to claim 6 , comprising
melt-kneading said recovery, a plasticizer, and a polyvinyl acetal (III) having an acetalization degree of 55 to 85 mol %, a content of a vinyl ester monomer unit of 0.1 to 15 mol % and a viscosity-average degree of polymerization of 1,400 to 5,000, to obtain the melt-kneaded product; and
then forming a film from the melt-kneaded product.