Electrically conductive, olefin multiblock copolymer compositions
Free radically crosslinked, electrically conductive compositions exhibiting a highly stable volume resistivity comprise an olefin multiblock copolymer (OBC) and a conductive filler, e.g., a conductive carbon black. These compositions exhibit a highly stable volume resistivity relative to a composition similar in essentially all aspects save that the OBC is replaced with a conventional polyethylene of similar density and melt index.
1. A composition comprising-on weight percent based on the weight of the composition:
(A). 60 to 99% an ethylene-alpha-olefin multiblock interpolymer (OBC) (1) having a weight average molecular weight (Mw) of greater than (>) 40,000 grams per mole (g/mol), (2) having a molecular weight distribution (Mw/Mn) of 1.7 to 3.5, and (3) comprising one or more hard segments and one or more soft segments, the hard and soft segments having a difference of alpha-olefin content of less than 18.5 mole percent (mol %), and
(B). 40 to 1% conductive filler.
2. The composition of claim 1 further comprising at least one of:
(C). An elastomer other than an OBC,
(D). A plasticizer,
(E). A cure agent, and
(F). One or more additives.
3. The composition of claim 2 in which the conductive filler is at least one of carbon black, conductive carbon and metal particles.
4. The composition of claim 2 in which the conductive filler is at least one of graphene and carbon nanotubes.
5. The composition of claim 3 further comprising at least one of aluminum, zinc, iron, nickel, tin, lead, and silver.
6. The composition of claim 3 in which the elastomer other than an OBC is present in an amount of 1 to 35 wt % based on the weight of the composition, and is at least one of a polyolefin homopolymer and interpolymer.
7. The composition of claim 3 in which the elastomer other than an OBC is present in an amount of 1 to 35 wt % based on the weight of the composition, and is a non-olefin elastomer comprising at least one of silicone elastomer, urethane elastomer, styrene-butadiene rubber (SBR), nitrile rubber, chloroprene, fluoroelastomer, perfluoroelastomer, polyether block amide and chlorosulfonated polyethylene.
8. The composition of claim 3 in which the plasticizer is present in an amount of 1 to 20 wt % based on the weight of the composition.
9. The composition of claim 6 in which at least one of the OBC and elastomer comprises silane functionality.
10. The composition of claim 3 in which the cure agent is present and is at least one of an organic base, carboxylic acid, sulfonic acid, and an organometallic compound.
11. The composition of claim 1 free of halogen.
12. A wire or cable article comprising the composition of claim 1 .