Process for producing C

1. A process for producing a reaction mixture comprising a plurality of C 3 chlorinated alkane isomers comprising chlorinating a C 3 chlorinated alkane starting material in a chlorination zone to produce the plurality of C 3 chlorinated alkane isomers, the plurality of C 3 chlorinated alkane isomers each having at least one more chlorine atom than the C 3 chlorinated alkane starting material, wherein the concentration of the C 3 chlorinated alkane starting material is controlled such that conversion of the C 3 chlorinated alkane starting material to the plurality of C 3 chlorinated alkane isomers, represented by the molar ratio of the C 3 chlorinated alkane starting material:C 3 chlorinated alkane isomers in the reaction mixture present in the chlorination zone, does not exceed about 40:60, wherein said plurality of C 3 chlorinated alkane isomers comprises a first isomer and a second isomer, and wherein the molar ratio of the first isomer:second isomer in the plurality of isomers produced in the chlorination zone is 40:60 to about 60:40.

2. A process for producing a reaction mixture comprising a plurality of C 3 chlorinated alkane isomers comprising chlorinating a C 3 chlorinated alkane starting material in a chlorination zone to produce the plurality of C 3 chlorinated alkane isomers, the plurality of C 3 chlorinated alkane isomers each having at least one more chlorine atom than the C 3 chlorinated alkane starting material, wherein the concentration of the C 3 chlorinated alkane starting material is controlled such that conversion of the C 3 chlorinated alkane starting material to the plurality of C 3 chlorinated alkane isomers, represented by the molar ratio of the C 3 chlorinated alkane starting material:C 3 chlorinated alkane isomers in the reaction mixture present in the chlorination zone, does not exceed about 40:60, wherein the reaction mixture is extracted from the chlorination zone and subjected to subsequent chlorination steps in 1, 2, 3, or 4 sequentially arranged downstream chlorination zones, wherein the molar ratio of the C 3 chlorinated alkane starting material:C 3 chlorinated alkane isomers in the reaction mixture present in any of the downstream chlorination zones does not exceed about 40:60.

3. A process for producing a reaction mixture comprising a plurality of C 3 chlorinated alkane isomers comprising chlorinating a C 3 chlorinated alkane starting material in a chlorination zone to produce the plurality of C 3 chlorinated alkane isomers, the plurality of C 3 chlorinated alkane isomers each having at least one more chlorine atom than the C 3 chlorinated alkane starting material, wherein the concentration of the C 3 chlorinated alkane starting material is controlled such that conversion of the C 3 chlorinated alkane starting material to the plurality of C 3 chlorinated alkane isomers, represented by the molar ratio of the C 3 chlorinated alkane starting material:C 3 chlorinated alkane isomers in the reaction mixture present in the chlorination zone, does not exceed about 40:60, wherein the process further comprises one or more distillation steps on the reaction mixture, said one or more distillation steps being carried out using distillation apparatus in direct communication with the chlorination zone and/or being carried out on reaction mixture extracted from the chlorination zone using distillation apparatus remote from the chlorination zone, and wherein the process further comprises the steps of feeding a mixture into an aqueous treatment zone, contacting the mixture with an aqueous medium and extracting a treated mixture comprising reduced levels of oxygenated compounds, wherein the mixture is a reaction mixture extracted from the chlorination zone, a plurality of C 3 chlorinated alkane isomer stream obtained via distillation from the reaction mixture or a partially distilled reaction mixture, wherein the partially distilled reaction mixture is a reaction mixture extracted from the chlorination zone from which one or more of an unreacted C 3 chlorinated alkane starting material stream, one or more single isomer streams and/or one or more distillation residue streams has already been obtained via distillation.

4. The process of claim 3 , wherein the treated mixture comprises oxygenated organic compounds in amounts of about 1000 ppm or less.

5. The process of claim 3 , wherein the aqueous treatment step precedes none, one, some or all of the distillation step/s.

6. A process for producing a reaction mixture comprising a plurality of C 3 chlorinated alkane isomers comprising chlorinating a C 3 chlorinated alkane starting material in a chlorination zone to produce the plurality of C 3 chlorinated alkane isomers, the plurality of C 3 chlorinated alkane isomers each having at least one more chlorine atom than the C 3 chlorinated alkane starting material, wherein the concentration of the C 3 chlorinated alkane starting material is controlled such that conversion of the C 3 chlorinated alkane starting material to the plurality of C 3 chlorinated alkane isomers, represented by the molar ratio of the C 3 chlorinated alkane starting material:C 3 chlorinated alkane isomers in the reaction mixture present in the chlorination zone, does not exceed about 40:60, wherein the process further comprises one or more distillation steps on the reaction mixture, said one or more distillation steps being carried out using distillation apparatus in direct communication with the chlorination zone and/or being carried out on reaction mixture extracted from the chlorination zone using distillation apparatus remote from the chlorination zone, and wherein the chlorination zone is conducted in a falling film tubular photoreactor and the molar ratio of the C 3 chlorinated alkane starting material:C 3 chlorinated alkane isomers in the reaction mixture does not exceed about 40:60.