Composite sheet for forming protective film
A protective film-forming composite sheet 10 comprises a pressure sensitive adhesive sheet 16 in which a pressure sensitive adhesive layer 12 is provided on a base material 11 , a protective film-forming film 13 , and a release film 14 . When α (mN/25 mm) represents the maximum peel force between the protective film-forming film 13 and the release film 14 ; β (mN/25 mm) represents the minimum peel force between the pressure sensitive adhesive sheet 16 and the protective film-forming film 13 ; and γ (mN/25 mm) represents the maximum peel force between the pressure sensitive adhesive sheet 16 and the protective film-forming film 13 , the following relationships (1) to (3) hold for α, β, and γ; β≥70 (1) α/β≤0.50 (2) γ≤2000 (3).
1. A protective film-forming composite sheet, comprising:
a pressure sensitive adhesive sheet in which a pressure sensitive adhesive layer is provided on a base material,
a protective film-forming film bonded to the pressure sensitive adhesive layer, and
a release film bonded to a surface of the protective film-forming film opposite to a surface bonded to the pressure sensitive adhesive layer,
wherein when α by mN/25 mm represents a maximum peel force between the protective film-forming film and the release film; β by mN/25 mm represents a minimum peel force between the pressure sensitive adhesive sheet and the protective film-forming film; and γ by mN/25 mm represents a maximum peel force between the pressure sensitive adhesive sheet and the protective film-forming film, as measured using a test piece having a width of 25 mm at a peel angle of 180 degrees, a measurement temperature of 23° C., a peel rate of 300 mm/min, and a measurement length of 100 mm in which 10 mm at the start and 10 mm at the end of measurement are excluded from the effective value, the minimum peel force β and the maximum peel force γ are obtained by measuring a load when the pressure sensitive adhesive sheet is peeled from the protective film-forming film, and the minimum value and the maximum value among the resulting measured values of the load are defined as the minimum peel force β and the maximum peel force γ, respectively, the following relationships (1) to (3) hold for α, β, and γ:
β≥70 (1)
α/β≤0.50 (2)
γ≤2000 (3), and
wherein the protective film-forming film comprises a filler in an amount of from 55 to 80% by mass.
2. The protective film-forming composite sheet according to claim 1 , wherein when γ′ by mN/25 mm represents a maximum peel force between the protective film-forming film after curing and the pressure sensitive adhesive sheet as measured using a test piece having a width of 25 mm at a peel angle of 180 degrees, a measurement temperature of 23° C., and a peel rate of 300 mm/min, the following relationship (4) is satisfied:
γ′≤2000 (4).
3. The protective film-forming composite sheet according to claim 2 , wherein the base material is a polypropylene film or a cross-linked film thereof, or a laminated film of at least one of these films and another film.
4. The protective film-forming composite sheet according to claim 1 , wherein the pressure sensitive adhesive layer comprises a non-energy ray-curable pressure sensitive adhesive or a pressure sensitive adhesive obtained by curing an energy ray-curable pressure sensitive adhesive.
5. The protective film-forming composite sheet according to claim 2 , wherein the pressure sensitive adhesive layer comprises a non-energy ray-curable pressure sensitive adhesive or a pressure sensitive adhesive obtained by curing an energy ray-curable pressure sensitive adhesive.
6. The protective film-forming composite sheet according to claim 3 , wherein the pressure sensitive adhesive layer comprises a non-energy ray-curable pressure sensitive adhesive or a pressure sensitive adhesive obtained by curing an energy ray-curable pressure sensitive adhesive.
7. The protective film-forming composite sheet according to claim 1 , wherein the minimum peel force β is 250 mN/25 mm or more.