Separator and lithium battery including the separator
A separator including a porous base material layer and a coating layer disposed on at least one surface of the porous base material layer, wherein the coating layer includes the binder composition, and a binder film comprising the binder composition has an elongation of 10% or less measured after maintaining the binder film under a load of 50 g at 150° C. for 10 minutes, and a lithium battery including the same.
1. A separator comprising:
a porous base material layer; and
a coating layer disposed on at least one surface of the porous base material layer,
wherein the coating layer comprises a filler and a binder composition,
wherein the binder composition comprises:
first polymer nanoparticles having an average particle diameter of about 90 nm or less, wherein the glass transition temperature of the first polymer nanoparticles is about 60° C. or higher; and
a first polymer binder having a glass transition temperature of about 20° C. or less,
wherein, within the binder composition, the first polymer nanoparticles are in an amount of about 7 to about 60 parts by weight based on 100 parts by weight of the first polymer binder.
2. The separator of claim 1 , wherein an elongation of a binder film comprising the binder composition measured after maintaining the binder film under a load of 50 g at 150° C. for 10 minutes is about 10% or less.
3. The separator of claim 1 , wherein a breaking strength of the binder film comprising the binder composition measured after being immersed in an electrolytic solution is about 40 Kg/cm 2 or greater.
4. The separator of claim 1 , wherein the binder composition has a storage modulus of about 30 MPa or greater at 100° C.
5. The separator of claim 1 , wherein the polymer particles are polyurethane.
6. The separator of claim 1 , wherein the first polymer binder has a gel content of about 90% or less.
7. The separator of claim 1 , wherein the binder composition further comprises a binding agent to chemically bind the first nanoparticles with the first polymer binder.
8. The separator of claim 1 , wherein the filler has an average particle diameter of about 300 nm to about 2.0 μm.
9. The separator of claim 1 , wherein an amount of the filter is about 50% by weight to about 99% by weight based on the total weight of the coating layer.
10. The separator of claim 1 , wherein the porous base material layer comprises polyolefin.
11. The separator of claim 1 , wherein the first polymer binder comprises a diene-based polymer prepared by polymerizing a monomer composition comprising diene-based monomers.
12. The separator of claim 11 , wherein the diene-based monomers comprise 1,3-butadiene, isoprene, 2-chloro-1,3-butadiene, 2,3-dimethyl-1,3-butadiene, 2-ethyl-1,3-butadiene, 1,3-pentadiene, chloroprene, vinylpyridine, vinyl norbornene, dicyclopentadiene, and 1,4-hexadiene.
13. The separator of claim 1 , having a shrinkage of about 40% or less after being maintained at 150° C. for 10 minutes.
14. The separator of claim 1 , further comprising an adhesive layer disposed on the coating layer.
15. The separator of claim 14 , wherein the adhesive layer comprises: the same binder as that of the coating layer; a binder different from that of the coating layer and comprising an acrylate-based binder, a fluorinated binder, a rubber binder or any combination thereof; a binder comprising inorganic particles, organic particles, or any combination thereof, and an organic polymer; or any combination thereof.
16. The separator of claim 15 , wherein the organic particles have a particle diameter of about 1 nm to about 100 nm.
17. A lithium battery comprising the separator of claim 1 .