Smoking articles containing polymers of polycarboxylic acid esters
Disclosed is a smoking article containing a rod containing a smokable composition, an optional wrapper for the rod, and at least one polymer or oligomer comprising monomer units of a polycarboxylic acid ester disposed on or in the rod, the wrapper, or both. The polycarboxylic acid ester contains an acid moiety having at least two carboxylic groups, and at least two alcohol moieties independently selected from those corresponding to a cycloalkyl alcohol or an aryl alcohol. The cycloalkyl alcohol or aryl alcohol is a flavorant, or chemesthetic agent, or both. In addition, a method for the controlled release of these flavorant or chemesthetic agents is described, which comprises pyrolyzing at least one polymer or oligomer.
1. A method for controlling the release of flavorant or chemesthetic agent comprising a cycloalkyl alcohol or aryl alcohol, comprising:
pyrolyzing at least one polymer or oligomer comprising monomer units of a polycarboxylic acid ester,
wherein said polycarboxylic acid ester comprises an acid moiety comprising at least two carboxylate groups, and at least two esterifying alcohol moieties independently selected from those corresponding to a cycloalkyl alcohol or an aryl alcohol comprising the flavorant or chemesthetic agent.
2. The method of claim 1 , wherein the monomer units comprise dicarboxylic acid diesters.
3. The method of claim 1 , further comprising incorporating said at least one polymer or oligomer into a smoking article, prior to said pyrolyzing.
4. The method of claim 3 , wherein said incorporating comprises disposing said at least one polymer or oligomer on or in a rod of a smoking composition, on or in a wrapper for a rod of a smoking composition, or on or in a filter, or some combination of these.
5. The method of claim 4 , wherein said monomer units comprise one or more diesters of one or more dicarboxylic acids.
6. The method of claim 1 , wherein said cycloalkyl alcohol or aryl alcohol comprise one or more of menthol, thymol, or eugenol.
7. The method of claim 1 , wherein said acid moiety comprises one or more selected from 1-carboxy-1-carboxymethylethylene, or 1,2-dicarboxyethylene.
8. The method of claim 1 , wherein said monomer units comprise those resulting from free radical polymerization or oligomerization of at least one of dimenthyl itaconate, dimenthyl maleate, or dimenthyl fumarate.
9. The method of claim 8 , wherein said monomer units comprise those resulting from free radical polymerization or oligomerization of dimenthyl itaconate.
10. The method of claim 1 , wherein said at least one polymer or oligomer further comprises one or more monomer units different from said monomer units of said polycarboxylic acid ester, and resulting from free radical polymerization or oligomerization of one or more co-monomers.
11. The method of claim 10 , wherein said one or more co-monomers comprises an unsaturated carboxylic acid or ester.
12. The method of claim 11 , wherein said unsaturated carboxylic acid or ester comprises one or more of acrylic acid, methacrylic acid, methyl acrylate, or methyl methacrylate.
13. The method of claim 1 , wherein the cycloalkyl alcohol or aryl alcohol are linked to a polymeric backbone through a non-carbonate linking group.