IP Library Granted Patent US 10,047,610
Granted Patent B2
US 10,047,610 · App. 14/847,794 · Granted Aug 14, 2018

Ceramic matrix composite materials with rare earth phosphate fibers and methods for preparing the same

Inventors: Bahram Jadidian (Watchung, NJ); Eric Passman (Piscataway, NJ)
Assignee: HONEYWELL INTERNATIONAL INC.
F01D5/147C04B35/447C04B35/624C04B35/803D03D15/12D06M11/45D06M11/46D06M11/47F01D5/282F01D5/284F23R3/007C04B2235/3217C04B2235/3224C04B2235/3225C04B2235/3227C04B2235/3229C04B2235/3427C04B2235/3463C04B2235/447C04B2235/522C04B2235/5224C04B2235/5228C04B2235/5256C04B2235/5272C04B2235/616D06M2101/00F05D2240/11F05D2300/15F05D2300/6033
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Quick Facts
Patent No.
US 10,047,610
App. No.
14/847,794
Granted
Aug 14, 2018
Kind
B2
Abstract

Disclosed is a ceramic matrix composite (CMC) material including rare earth phosphate ceramic fibers embedded in a ceramic matrix, wherein the ceramic matrix also optionally includes a rare earth phosphate material. Methods for manufacturing the CMC material and gas turbine engine components formed of the CMC material are also disclosed.

Claims (23)

1. A ceramic matrix composite (CMC) material comprising rare earth phosphate ceramic fibers consisting of YPO 4 or YbPO 4 embedded in a ceramic matrix, wherein the ceramic matrix comprises a rare earth phosphate material.

2. The CMC material of claim 1 , wherein the rare earth phosphate ceramic fibers are present in an amount, based on an overall volume of ceramic fibers in the CMC material, of about 5% to about 95% by volume.

3. The CMC material of claim 1 , further comprising ceramic fibers consisting of aluminosilicate or alumina embedded in the ceramic matrix.

4. The CMC material of claim 1 , wherein the ceramic matrix further comprises alumina, aluminosilicate, aluminum phosphate, or rare earth silicates.

5. The CMC material of claim 1 , wherein the rare earth phosphate material is present in an amount, based on an overall volume of ceramic matrix in the CMC material, of about 5% to about 95% by volume.

6. A method for manufacturing a ceramic matrix composite (CMC) material comprising the steps of:

weaving ceramic fibers into a mat structure, wherein the ceramic fibers comprise rare earth phosphate ceramic fibers;

infiltrating the ceramic fiber mat structure with a ceramic matrix precursor slurry to form a slurry-infiltrated ceramic fiber mat structure; and

heating the slurry-infiltrated ceramic fiber mat structure to form the CMC material.

7. The method of claim 6 , further comprising the step of manufacturing the ceramic fibers prior to the step of weaving the ceramic fibers.

8. The method of claim 7 , wherein the step of manufacturing the ceramic fibers is performed using a sol-gel process.

9. The method of claim 6 , wherein the step of weaving ceramic fibers comprises weaving ceramic fibers that consist of a material selected from the group consisting of: LaPO 4 , YPO 4 , CePO 4 , ScPO 4 , PrPO 4 , NdPO 4 , SmPO 4 , EuPO 4 , HoPO 4 , TmPO 4 , ErPO 4 , YbPO 4 , LuPO 4 , DyPO 4 , TbPO 4 , GdPO 4 and combinations of two or more thereof.

10. The method of claim 6 , further comprising the step of manufacturing the ceramic matrix precursor slurry prior to the step of infiltrating the ceramic fiber mat structure.

11. The method of claim 10 , wherein the step of manufacturing the ceramic matrix precursor slurry comprises the sub-steps of:

heat treating an amorphous powder to remove volatile compounds therefrom and to transform the amorphous powder into a crystalline structure powder;

milling the crystalline structure powder to reduce a size of crystals in the crystalline structure powder; and

mixing the crystalline structure powder with a binder or dispersant to form the ceramic matrix precursor slurry.

12. The method of claim 11 , wherein the sub-step of heat treating the amorphous powder comprises heat treating a rare earth phosphate ceramic amorphous powder.

13. The method of claim 6 , wherein the step of heating the slurry-infiltrated ceramic fiber mat structure comprises heating at or above about 1000° C.

14. A gas turbine engine comprising a gas turbine engine component, wherein the gas turbine engine component is formed at least in part of a ceramic matrix composite (CMC) material, and wherein the CMC material comprises rare earth phosphate ceramic fibers consisting of YPO 4 or YbPO 4 embedded in a ceramic matrix.

15. The gas turbine engine of claim 14 , wherein the gas turbine engine component is selected from the group consisting of: a blade, a vane, a nozzle, a duct, and a combustion liner.

16. The gas turbine engine of claim 14 , wherein the gas turbine engine component further comprises an insulating material layer overlaying the CMC material, and wherein the insulating material layer comprises a rare earth phosphate ceramic material.

17. The gas turbine engine of claim 16 , wherein the gas turbine engine component further comprises protective outer coating overlaying the insulating material layer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 8, 2015
From: JADIDIAN, BAHRAM; PASSMAN, ERIC
To: HONEYWELL INTERNATIONAL INC.
Reel/Frame 036512/0626 →
Continuity (1)
Related Publication 20170067345A1 · Mar 9, 2017
Cited By (1)
US 12,325,670