Triboelectric energy generator using control of dipole polarization direction and method of fabricating thereof
Provided are a triboelectric energy generator using a control of a dipole polarization direction and a method of fabricating the same. The present invention controls a direction of a charging property generated by friction through a control of a dipole polarization using a ferroelectric or piezoelectric property of a material, and by using this control, the present invention is related to a triboelectric energy generator in a disk type in which a frictional charging material is slidable on a thin film only using control of a dipole polarization without need of an additional patterning process and output power is improved.
1. A triboelectric energy generator using a control of a dipole polarization direction, comprising:
a lower electrode layer;
a ferroelectric or piezoelectric material layer disposed on the lower electrode layer; and
a frictional charging material layer which is disposed on the ferroelectric or piezoelectric material layer in a contact state, is movable, and is an upper electrode,
wherein the ferroelectric or piezoelectric material layer is divided into two or more regions in a direction parallel to a surface of the lower electrode layer,
in the two or more regions of the ferroelectric or piezoelectric material layer, each region is polarized so that dipole polarization directions of the regions disposed next to each other are different from each other, and
triboelectric energy is generated by continuous charging and friction caused by sliding or rotating the frictional charging material layer.
2. A triboelectric energy generator using a control of a dipole polarization direction, comprising:
a lower electrode layer;
a ferroelectric or piezoelectric material layer disposed on the lower electrode layer;
a frictional charging material layer disposed on the ferroelectric or piezoelectric material layer in a contact state and configured to be movable; and
an upper electrode layer disposed on the frictional charging material layer,
wherein the ferroelectric or piezoelectric material layer is divided into two or more regions in a direction parallel to a surface of the lower electrode layer,
in the two or more regions of the ferroelectric or piezoelectric material layer, each region is polarized so that dipole polarization directions of the regions disposed next to each other are different from each other, and
triboelectric energy is generated by continuous charging and friction caused by sliding or rotating the frictional charging material layer.
3. The triboelectric energy generator of claim 1 , further comprising withdrawable parts respectively connected to the lower electrode and the upper electrode, wherein an energy storage part is connected to the withdrawable parts.
4. The triboelectric energy generator of claim 3 , wherein rectifier diodes are connected between the withdrawable parts and the energy storage part.
5. A method of fabricating a triboelectric energy generator using a control of a dipole polarization direction, comprising:
(i) providing a lower electrode layer;
(ii) disposing a ferroelectric or piezoelectric material layer on the lower electrode layer;
(iii) disposing a frictional charging material layer which is disposed on the ferroelectric or piezoelectric material layer in a contact state and is a movable upper electrode;
(iv) applying an external voltage to the lower electrode layer and the frictional charging material layer, polarizing a dipole of the ferroelectric or piezoelectric material layer in one direction, and forming a first region; and
(v) moving the frictional charging material layer until the frictional charging material layer passes from the first region, applying an external voltage to the lower electrode layer and the frictional charging material layer in a direction opposite a voltage direction when the first region is formed, polarizing a dipole of the ferroelectric or piezoelectric material layer to have a different polarization direction from the dipole polarization direction of the first region, and forming a second region,
wherein the operation (v) is repeatable multiple times based on the number of regions of the ferroelectric or piezoelectric material layer.
6. A method of fabricating a triboelectric energy generator using a control of a dipole polarization direction, comprising:
(i) providing a lower electrode layer;
(ii) disposing a ferroelectric or piezoelectric material layer on the lower electrode layer;
(iii) disposing a frictional charging material layer which is disposed on the ferroelectric or piezoelectric material layer in a contact state, is movable, and has a separate upper electrode;
(iv) applying an external voltage to the lower electrode layer and the frictional charging material layer, polarizing a dipole of the ferroelectric or piezoelectric material layer in one direction, and forming a first region; and
(v) moving the frictional charging material layer until the frictional charging material layer passes from the first region, applying an external voltage to the lower electrode layer and the frictional charging material layer in a direction opposite a voltage direction when the first region is formed, polarizing a dipole of the ferroelectric or piezoelectric material layer to have a different polarization direction from the dipole polarization direction of the first region, and forming a second region, wherein the operation (v) is repeatable multiple times based on the number of regions of the ferroelectric or piezoelectric material layer.
7. The method of claim 5 , further comprising:
connecting respective withdrawable parts to the lower electrode and the upper electrode; and
connecting an energy storage part to the withdrawable parts.
8. The method of claim 7 , wherein rectifier diodes are connected between the withdrawable parts and the energy storage part.