Rechargeable lithium battery
Disclosed is a rechargeable lithium battery including a positive electrode including a positive active material; a negative electrode including a negative active material; an electrolyte solution including a lithium salt and a non-aqueous organic solvent; and a separator between the positive and the negative electrodes, the separator including a porous substrate and a coating layer positioned on at least one side of the porous substrate. The negative active material includes a Si-based material; the non-aqueous organic solvent includes cyclic carbonate including ethylene carbonate, propylene carbonate, or combinations thereof, the cyclic carbonate being included in an amount of about 20 volume % to about 60 volume % based on the total amount of the non-aqueous organic solvent; and the coating layer includes a fluorine-based polymer, an inorganic compound, or combinations thereof. The rechargeable lithium battery has improved cycle-life and high temperature storage characteristics.
1. A rechargeable lithium battery comprising:
a positive electrode comprising a positive active material;
a negative electrode comprising a negative active material comprising a Si-based material;
an electrolyte solution consisting of:
a lithium salt selected from LiPF 6 , LiSbF 6 , LiAsF 6 , LiC 4 F 9 SO 3 , LiAlO 2 , LiAlCl 4 , LiN(C x F 2x+1 SO 2 )(C y F 2y+1 SO 2 ), wherein, x and y are natural numbers, LiCl, LiI, LiB(C 2 O 4 ) 2 , and combinations thereof,
a non-aqueous organic solvent consisting of a cyclic carbonate selected from the group consisting of ethylene carbonate, propylene carbonate, and combinations thereof, and a linear carbonate selected from the group consisting of ethylmethyl carbonate, diethyl carbonate, and combinations thereof; the cyclic carbonate being included in an amount of about 20 volume % to about 60 volume % based on the total amount of the non-aqueous organic solvent, and
an additive selected from fluoroethylene carbonate, succinonitrile, adiponitrile, and combinations thereof; the additive being included in an amount of about 15 parts by weight to about 30 parts by weight based on 100 of the non-aqueous organic solvent; and
a separator between the positive electrode and the negative electrode, the separator comprising a porous substrate and a coating layer positioned on at least one side of the porous substrate and comprising a fluorine-based polymer or a combination of fluorine-based polymer and an inorganic compound,
wherein the fluorine-based polymer is about 1 g/m 2 to about 3 g/m 2 in the coating layer, or the combination of fluorine-based polymer and inorganic compound is about 2 g/m 2 to about 6 g/m 2 in the coating layer.
2. The rechargeable lithium battery of claim 1 , wherein the Si-based material comprises Si, silicon oxide, a Si—C composite, a silicon-based alloy, or a combination thereof.
3. The rechargeable lithium battery of claim 1 , wherein the porous substrate comprises polyethylene, polypropylene, aramid, polyimide, or a combination thereof.
4. The rechargeable lithium battery of claim 1 , wherein the fluorine-based polymer comprises polyvinylidene fluoride (PVdF), a polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP) copolymer, or a combination thereof.
5. The rechargeable lithium battery of claim 1 , wherein the inorganic compound comprises Al 2 O 3 , MgO, TiO 2 , Al(OH) 3 , Mg(OH) 2 , Ti(OH) 4 , or a combination thereof.
6. The rechargeable lithium battery of claim 1 , wherein a ratio of the amount of the additive to the amount of the cyclic carbonate is about 0.25 wt %/vol % to 1.5 wt %/vol %.