Formation of 2D flakes from chemical cutting of prefabricated nanoparticles and van der Waals heterostructure devices made using the same
A method of synthesis of two-dimensional (2D) nanoflakes comprises the cutting of prefabricated nanoparticles. The method allows high control over the shape, size and composition of the 2D nanoflakes, and can be used to produce material with uniform properties in large quantities. Van der Waals heterostructure devices are prepared by fabricating nanoparticles, chemically cutting the nanoparticles to form nanoflakes, dispersing the nanoflakes in a solvent to form an ink, and depositing the ink to form a thin film.
1. A method of fabricating a two-dimensional nanoflake comprising:
fabricating a nanoparticle; and
refluxing the nanoparticle in a solvent to form the two-dimensional nanoflake.
2. The method of claim 1 , wherein the solvent is a coordinating solvent.
3. The method of claim 1 , wherein the solvent is selected from the group consisting of: amines; fatty acids; phosphines; phosphine oxides; and alcohols.
4. The method of claim 1 , wherein the solvent is hexadecylamine or myristic acid.
5. The method of claim 1 , wherein the nanoparticle is a quantum dot.
6. The method of claim 1 , wherein the nanoparticle is a nanorod.
7. A method of fabricating a two-dimensional nanoflake comprising:
fabricating a nanoparticle;
stirring the nanoparticle in a first solvent in the presence of a first intercalating agent and a second intercalating agent for a first time period; and
adding a second solvent and stirring for a second time period.
8. The method of claim 7 , wherein the first and second intercalating agents are selected from the group consisting of: Lewis bases; aminothiols; and amino acids.
9. The method of claim 7 , wherein the first and second solvents are selected from the group consisting of: dimethyl sulfoxide; acetonitrile; and propanol.
10. The method of claim 7 , further comprising:
adding a third intercalating agent and a third solvent; and
stirring for a third time period.
11. The method of claim 7 , wherein the nanoparticle is a quantum dot.
12. The method of claim 7 , wherein the nanoparticle is a nanorod.
13. A method of preparing a van der Waals heterostructure device comprising:
fabricating nanoparticles;
chemical cutting of the nanoparticles to form two-dimensional nanoflakes;
dispersing the nanoflakes in a solvent to form an ink; and
depositing the ink to form a thin film.
14. The method of claim 13 , wherein the nanoparticles are selected from the group consisting of: graphene; transition metal dichalcogenides; transition metal trichalcogenides; Group 13-16 compounds; Group 15-16 compounds; hexagonal boron nitride; oxides; phosphides; Group 14 elements; Group 12-16 compounds; Group 13-15 compounds; I-III-VI compounds; and metals; and their doped derivatives and alloys.
15. The method of claim 13 , wherein the nanoparticles are MoS 2 nanoparticles.
16. The method of claim 13 , wherein the nanoparticles are quantum dots.
17. The method of claim 13 , wherein the nanoparticles are nanorods.
18. A method of fabricating two-dimensional nanoflakes, the method comprising:
fabricating a nanoparticle; and
refluxing the nanoparticle in a solvent to convert the nanoparticle into a plurality of two-dimensional nanoflakes.
19. The method of claim 18 , wherein the nanoparticle is a 3D nanoparticle.
20. The method of claim 18 , wherein the nanoparticle is a 0D nanoparticle.
21. The method of claim 18 , wherein the nanoparticle is a nanorod.