Sodium carbonate monohydrate crystallization

1. A method for preparing solid sodium carbonate monohydrate (Na 2 CO 3 .1H 2 O), the method comprising:

reducing the pressure of a vessel containing a solution comprising sodium carbonate and sodium chloride in an aqueous media to between 0.1 and 0.80 atmospheres with the result that the boiling point of the solution decreases below the Na 2 CO 3 .1H 2 O to anhydrous Na 2 CO 3 transition temperature;

evaporating at least a portion of the aqueous media at the reduced pressure; and

isolating the sodium carbonate monohydrate in solid form.

2. The method according to claim 1 , wherein the aqueous media is water.

3. The method according to claim 1 , wherein the sodium chloride is present in an amount greater than 0 but less than 32 wt percent.

4. The method according to claim 1 , wherein the sodium chloride is present in an amount between 5 wt percent and 10 wt percent.

5. The method according to claim 1 , wherein the sodium chloride is present in an amount between 3 wt percent and 5 wt percent.

6. The method according to claim 1 , wherein the sodium sulfate is present in an amount greater than 0 but less than 4 wt percent.

7. The method according to claim 1 , wherein the solid sodium carbonate monohydrate is in a crystalline form.

8. The method according to claim 7 , wherein the crystalline form is orthorhombic.

9. The method according to claim 1 , wherein the vessel is a mechanical vapor recompression (MVR) crystallizer or a multiple effect evaporation crystallizer.

10. The method according to claim 1 , wherein the vessel is at a temperature in the range of 50 to 110° C.