Electrolyte composition for a lithium-ion battery
An electrolyte composition for a lithium-ion battery, a lithium-ion battery, and also the use of a fluorine-containing cyclic carbonate component and lithium nitrate for improving the cycle stability and/or for increasing the performance of a lithium-ion battery.
1. An electrolyte composition for a lithium-ion battery with at least one cathode and at least one anode, the electrolyte composition comprising:
at least one aprotic nonaqueous solvent;
one fluorine-containing cyclic carbonate component; and
at least two lithium salts,
wherein one of the lithium salts is lithium nitrate, which is present in a quantity from 0.05% to 20% by weight relative to a total weight of the electrolyte composition,
wherein the fluorine-containing cyclic carbonate component is present in a quantity from 5% to 12% by weight relative to the total weight of the electrolyte composition,
wherein the anode is a silicon anode or a silicon/carbon composite anode, and wherein the electrolyte composition contains lithium bis(fluorosulfonyl)imide as an additional lithium salt.
2. The electrolyte composition according to claim 1 , wherein the fluorine-containing cyclic carbonate component is fluoroethylene carbonate.
3. A lithium-ion battery comprising:
a casing;
a battery core having at least one cathode and at least one anode, wherein the anode is a silicon anode or a silicon/carbon composite anode; and
an electrolyte composition according to claim 1 .
4. The electrolyte composition according to claim 1 , wherein the fluorine-containing cyclic carbonate component and lithium nitrate improve a cycle stability of a lithium-ion battery.
5. The electrolyte composition according to claim 1 , wherein the fluorine-containing cyclic carbonate component and lithium nitrate increase a performance of a lithium-ion battery.
6. The electrolyte composition according to claim 1 , wherein the fluorine-containing cyclic carbonate component and lithium nitrate form a surface layer on the anode.
7. The electrolyte composition according to claim 6 , further comprising vinylene carbonate.
8. The lithium-ion battery according to claim 3 , wherein the battery core further comprises at least one separator element.
9. The lithium-ion battery according to claim 8 , wherein the at least one separator element has a microporous structure.
10. The electrolyte composition according to claim 1 , wherein the at least one aprotic nonaqueous solvent is propylene carbonate (PC), ethylene carbonate (EC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), tetrahydrofuran (THF), 1,2-dimethoxyethane (DME), 2-methyltetrahydrofuran (2Me-THF), vinylene carbonate (VC), N-methylpyrrolidone (NMP), acetonitrile, or ethyl acetate, or a combination thereof.
11. An electrolyte composition for a lithium-ion battery with at least one cathode and at least one anode, the electrolyte composition comprising:
at least one aprotic nonaqueous solvent;
one fluorine-containing cyclic carbonate component; and
at least two lithium salts,
wherein one of the lithium salts is lithium nitrate,
wherein the fluorine-containing cyclic carbonate component is present in a quantity from 5% to 12% by weight relative to the total weight of the electrolyte composition,
wherein the anode is a silicon anode or a silicon/carbon composite anode, and
wherein the electrolyte composition contains lithium bis(fluorosulfonyl)imide as an additional lithium salt.