Cohesively failing, non-staining hot melt adhesives
A non-pressure sensitive hot melt adhesive for use in mailer applications uses a styrenic block copolymer (SBC) with a hydrogenated mid-block as the primary polymer in the composition. The adhesive contains about 10% to about 50% by weight of the SBC, about 2% to about 30% by weight of a polyolefin polymer as a secondary polymer in the composition, about 10% to about 70% by weight of a suitable plasticizer, about 0% to about 30% by weight of a wax, about 0% to about 50% by weight of one or more tackifying resins, about 0.1% to about 4% by weight of a stabilizer, and about 0% to about 3% by weight of auxiliary additives, so that the viscosity of the composition is equal to or less than about 10,000 cP at 163° C. The formulation balances the cohesive and adhesive strength required to insure the adhesive fails cohesively to prevent paper tear. In addition, the presence of the secondary polymer allows additional oil absorption into the polymer, thus preventing oil from staining the substrates or surfaces without significantly increasing the viscosity.
1. A hot melt adhesive composition, comprising a blend of the following components:
a) about 10% to about 50% by weight of a primary polymer comprising a styrenic block copolymer with a hydrogenated mid-block;
b) about 2% to about 30% by weight of a secondary polyolefin polymer, said secondary polymer selected from the group consisting of a random polyolefin polymer, an amorphous poly-alpha-olefin (APAO), and mixtures thereof, and having a density from about 0.850 g/cm 3 to about 0.965 g/cm 3 , and a melt index equal or greater than 10 grams/10 minutes at 190° C./2.16 kg;
c) about 30% to about 70% by weight of a solid or liquid plasticizer;
d) 0% to about 30% by weight of a wax;
e) 0% to about 50% of a tackifying resin having a softening point of at least about 95° C.;
f) about 0.1% to about 4% by weight of a stabilizer;
g) 0% to about 3% by weight of auxiliary additives;
wherein the components total 100% by weight of the composition, and the viscosity of the composition is equal to or less than about 10,000 cP at 163° C., wherein the adhesive composition does not contain an olefin block coplymer.
2. The composition of claim 1 wherein said styrenic block copolymer comprises about 15% to about 40% by weight of the composition.
3. The composition of claim 1 wherein said styrenic block copolymer comprises about 20% to about 30% by weight of the composition.
4. The composition of claim 1 wherein said styrenic block copolymer has styrene endblocks of about 10% to about 40% by weight, and a melt index less than 30 grams/10 minutes at 230° C./5 kg.
5. The composition of claim 1 wherein said styrenic block copolymer is selected from the group consisting of styrene-ethylene-butylene (SEB), styrene-ethylene-butylene-styrene (SEBS), styrene-ethylene-propylene (SEP), styrene-ethylene-propylene-styrene (SEPS), and Styrene-ethylene-ethylene-propylene-styrene (SEEPS).
6. The composition of claim 1 wherein the secondary olefin polymer comprises about 5% to about 20% by weight of the composition.
7. The composition of claim 1 wherein the secondary olefin polymer comprises about 5% to about 15% by weight of the composition.
8. The composition of claim 1 wherein said secondary olefin polymer has a density from about 0.855 g/cm 3 to about 0.910 g/cm 3 , and a melt index greater than about 100 g/10 minutes at 190° C./2.16 kg.
9. The composition of claim 1 wherein said secondary olefin polymer comprises the random polyolefin polymer and the random polyolefin polymer comprises a copolymer of ethylene and a C 3 to C 20 alpha-olefin.
10. The composition of claim 1 wherein said secondary olefin polymer comprises the random polyolefin polymer and the random polyolefin polymer comprises a copolymer of propylene and a C 2 to C 20 alpha-olefin.
11. The composition of claim 1 wherein said secondary polyolefin polymer comprises the amorphous poly-alpha-olefin (APAO).
12. The composition of claim 11 wherein said amorphous poly-alpha-olefin is a homopolymer of propylene or a copolymer of propylene with one or more alpha-olefin co-monomer.
13. The composition of claim 1 wherein said plasticizer is selected from the group consisting of naphthenic oils, paraffinic oils and mineral oils.
14. The composition of claim 1 wherein said plasticizer comprises about 50% to about 70% by weight of said composition.
15. The composition of claim 1 wherein said plasticizer comprises about 60% to about 70% by weight of said composition.
16. The composition of claim 1 wherein said wax is selected from the group consisting of a paraffin wax, a microcrystalline wax, a synthetic wax, and a polyolefin wax.
17. The composition of claim 1 wherein said composition has a viscosity less than 5,000 cP at 163° C.
18. An article comprising a mailer stock and the adhesive composition of claim 1 .
19. The article of claim 18 wherein said mailer stock is comprised of standard paper mailer stock, regular printer paper, manila paper, ink jet photo paper or a polyamide film.
20. The composition of claim 1 wherein said styrenic block copolymer comprises about 23% to about 50% by weight of the composition.
21. The composition of claim 20 wherein said styrenic block copolymer comprises about 23.4% to about 50% by weight of the composition.
22. The composition of claim 1 wherein said plasticizer is liquid at ambient temperature.
23. The composition of claim 1 wherein said plasticizer comprises about 35% to about 70% by weight of said composition.