Biaxially oriented polyamide-based resin film, and production method therefor
To provide a biaxially oriented polyamide-based resin film being excellent in laminate strength, pin-hole resistance under a low-temperature environment, impact resistance, and transparency, and which retains satisfactory a good external appearance even after being sterilized in hot water. A biaxially oriented polyamide-based resin film comprising a polyamide resin and 1 to 5% by mass of a polyamide-based block copolymer, wherein the polyamide-based block copolymer comprises a hard part including a residue of cyclic lactam having 4 to 10 carbon atoms, and a soft part including a residue of polyoxypropylene glycol or polyoxytetramethylene glycol having a weight average molecular weight of 500 to 3000, and the content X of the hard part and the content Y and the weight average molecular weight Mw of the soft part satisfy the following formulae (1) and (2): X+Y= 100(parts by mass) (1) 478.74×Mw −0.2989 ≤Y ≤93(parts by mass) (2).
1. A biaxially oriented polyamide-based resin film comprising a polyamide resin and a polyamide-based block copolymer,
wherein
the polyamide-based resin film comprises 1 to 3% by mass of the polyamide-based block copolymer,
the polyamide-based block copolymer comprises a hard part including a residue of cyclic lactam having 4 to 10 carbon atoms, and a soft part including a residue of polyoxypropylene glycol or polyoxytetramethylene glycol, wherein the soft part has a number average molecular weight of 1000 to 3000, and the content X of the hard part, the content Y of the soft part, and the number average molecular weight Mn of the soft part satisfy the following formulae (1) and (2):
X+Y= 100(parts by mass) (1)
478.74×Mn − 0.2989 ≤Y≤ 93 (2),
the polyamide-based resin film has a haze measured in accordance with JIS-K-7105 of not more than 3.7%, and
the number of pin-holes generated in a laminated film formed by laminating a polyethylene film having a thickness of 40 μm on the biaxially oriented polyamide-based resin film is 2.1 or less.
2. The biaxially oriented polyamide-based resin film according to claim 1 , wherein the biaxially oriented polyamide-based resin film contains 0.05 to 0.30% by mass of ethylene-bis-stearic acid amide, and the biaxially oriented polyamide-based resin film contains 0.3 to 0.8% by mass of porous aggregated silica having a pore volume of 1.0 to 1.8 ml/g and an average particle size of 2.0 to 7.0 μm.
3. The biaxially oriented polyamide-based resin film according to claim 2 , wherein a layer configuration of the biaxially oriented polyamide-based resin film is a single layer configuration or a co-extrusion laminated configuration of two or more layers.
4. A method for producing the film according to claim 3 , wherein a polyamide-based resin sheet cooled and solidified by an electrostatic adhesion method is stretched in a longitudinal direction at two stages, then stretched in a lateral direction in a differential-temperature manner with the stretching end temperature being higher than the stretching start temperature, then subjected to a heat fixing treatment, then subjected to an initial relaxation treatment, and subjected to a re-relaxation treatment at a temperature lower than the initial relaxation temperature.
5. A method for producing the film according to claim 2 , wherein a polyamide-based resin sheet cooled and solidified by an electrostatic adhesion method is stretched in a longitudinal direction at two stages, then stretched in a lateral direction in a differential-temperature manner with the stretching end temperature being higher than the stretching start temperature, then subjected to a heat fixing treatment, then subjected to an initial relaxation treatment, and subjected to a re-relaxation treatment at a temperature lower than the initial relaxation temperature.
6. The biaxially oriented polyamide-based resin film according to claim 1 , wherein a layer configuration of the biaxially oriented polyamide-based resin film is a single layer configuration or a co-extrusion laminated configuration of two or more layers.
7. A method for producing the film according to claim 6 , wherein a polyamide-based resin sheet cooled and solidified by an electrostatic adhesion method is stretched in a longitudinal direction at two stages, then stretched in a lateral direction in a differential-temperature manner with the stretching end temperature being higher than the stretching start temperature, then subjected to a heat fixing treatment, then subjected to an initial relaxation treatment, and subjected to a re-relaxation treatment at a temperature lower than the initial relaxation temperature.
8. A method for producing the film according to claim 1 , wherein a polyamide-based resin sheet cooled and solidified by an electrostatic adhesion method is stretched in a longitudinal direction at two stages, then stretched in a lateral direction in a differential-temperature manner with the stretching end temperature being higher than the stretching start temperature, then subjected to a heat fixing treatment, then subjected to an initial relaxation treatment, and subjected to a re-relaxation treatment at a temperature lower than the initial relaxation temperature.
9. The biaxially oriented polyamide-based resin film according to claim 1 , wherein the polyamide-based resin film has a haze of not more than 3.6%.