Modified polypropylene compositions for reduced necking in extrusion film casting or extrusion coating processes
The present invention discloses a modified polypropylene composition with higher flow activation energy and reduced necking in extrusion film/coat, wherein the composition comprises long chain branched polypropylene; a free radical initiator; a primary antioxidant; a secondary antioxidant; an acid neutralizer; and optionally a multifunctional monomer. Further the said composition of polypropylene shows higher sensitivity of viscosity to temperature, with improved stretchability.
1. A composition for extrusion comprising:
an impact copolymer (ICP), having a density range from 0.9 to 0.95 g/cm 3 and melt flow rate or index of the impact copolymer (ICP) in the range from 0.5 to 2.5 g/10 min, and including a long chain branched polypropylene homopolymer (LCB-PP);
a peroxidicarbonate free radical initiator in the range of 2000-8000 ppm by weight having a formula R′ —OCOOCO—R, where R and R′ are identical or different and independently selected from branched or linear (C1-C5)alkyl, (C6-C12) alicyclic, cetyl, and [3-(isobutyryloxy)-2,2,4-trimethylpentyl];
a primary antioxidant in the range of 200 to 800 ppm by weight;
a secondary anti-oxidant;
an acid neutralizer; and
wherein the composition is devoid of acrylate and has a flow activation energy in the range of 40-60 kJ/mole during extrusion.
2. The composition according to claim 1 , wherein the peroxidicarbonate has a half life in the range of 0.1-1 min at the extrusion temperature of polypropylene.
3. The composition according to claim 1 , wherein said primary antioxidant is a hindered phenolic-type antioxidant selected from the group consisting of pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxy-phenyl)propionate); 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-triazine-2,4,6(1H,3H,5H)trione and 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene.
4. The composition according to claim 1 , wherein the secondary anti-oxidant is an organo phosphite or organo phosphonite, selected from the group consisting of tris(2,4-di-tert-butylphenyl) phosphate, bis(2,4-di-t-butylphenyl) pentaerythritol diphosphate, 2,4,6tri-t-butylphenyl-2-butyl-2-ethyl-1,3-propanediolphosphite, bis(2,4-dicumylphenyl) pentaerythritol diphosphite, tris[2-[[2,4,8,10-tetra-tert-butyldibenzo [d,f] [1,3,2] dioxaphosphepin-6-yl] oxy] ethyl] amine, and [4-[4-bis(2,4-ditert-butylphenoxy) phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane in the range of 400-1400 ppm by weight.
5. The composition according to claim 1 wherein the acid neutralizer is a metal salt, wherein the metal is selected from the group consisting of an alkali, an alkaline-earth and transition-metal, while the metal salt is selected from the group consisting of carbonate, stearate, hydroxide, acetate, oxide, alkoxide and a combination thereof in the range of 200-1000 ppm by wt.
6. The composition according to claim 1 , wherein necking during extrusion of the composition is reduced up to 50%.
7. The composition according to claim 1 , wherein the increase in die swell during extrusion of the composition is in the range of 50-100%.
8. The composition according to claim 1 , wherein the amount of the free radical initiator is in the range of 4000-6000 ppm by weight.
9. The composition according to claim 3 , wherein the amount of said primary antioxidant is in the range of 400 to 800 ppm by weight.
10. The composition according to claim 4 , wherein the amount of the secondary anti-oxidant is in the range of 500 to 1200 ppm by weight.
11. The composition according claim 5 wherein the amount of the metal salt is in the range of 300-900 ppm by wt.
12. The composition according to claim 5 wherein the metal of the metal salt is selected from the group consisting of Na, K, Ca, Zn, and Al.