Methods of forming self-aligned vias
Processing methods comprising selectively orthogonally growing a first material through a mask to provide an expanded first material are described. The mask can be removed leaving the expanded first material extending orthogonally from the surface of the first material. Further processing can create a self-aligned via.
1. A processing method comprising:
providing a substrate with a substrate surface comprising a first surface of a first material and a second surface of a second material different from the first material;
forming a mask on the substrate, the mask having an opening exposing at least a portion of the first surface and the second surface;
expanding the first material to orthogonally grow an expanded first material to a height greater than the second surface; and
removing the mask from the substrate to leave the first material extending orthogonally from the substrate surface.
2. The method of claim 1 , wherein expanding the first material causes the expanded first material to expand straight up from the first surface through the opening in the mask to a height greater than the mask.
3. The method of claim 1 , wherein expanding the first material comprises one or more of oxidizing or nitriding the first material.
4. The method of claim 3 , wherein the first material comprises one or more of Co, Mo, W, Ta, Ti, Ru, Rh, Cu, Fe, Mn, V, Nb, Hf, Zr, Y, Al, Sn, Cr or La.
5. The method of claim 4 , wherein oxidizing or nitriding the first material comprises exposing the first material to an oxidizing agent or nitriding agent comprising one or more of O 2 , O 3 , N 2 O, H 2 O, H 2 O 2 , CO, CO 2 , NH 3 , N 2 H 4 , NO 2 , N 2 , N 2 /Ar, N 2 /He or N 2 /Ar/He.
6. The method of claim 1 , wherein the first material comprises a metal and the second material comprises a dielectric.
7. The method of claim 1 , further comprising depositing a third material on the substrate surface, the third material surrounding the orthogonally grown expanded first material extending from the substrate surface.
8. The method of claim 7 , wherein the third material comprises a dielectric.
9. The method of claim 8 , wherein the third material is different from the first material and the second material.
10. The method of claim 9 , further comprising etching the expanded first material extending from the substrate surface through the third material to leave an opening through the third material.
11. The method of claim 10 , wherein etching the expanded first material comprises exposing the first material to a metal halide compound.
12. The method of claim 11 , wherein the metal halide compound has a different metal than the first material.
13. The method of claim 10 , further comprising depositing a gapfill metal on a surface of the third material, the gapfill metal filling the opening of the third material and forming electrical contact with the first material.
14. The method of claim 13 , wherein the gapfill metal is different from the first material.
15. The method of claim 13 , further removing the gapfill metal from the surface of the third material, leaving the gapfill metal in the openings of the third material.