Article of footwear with soil-shedding performance
The disclosure relates to articles of footwear and components thereof, including outsoles, which can be used in conditions normally conducive to the accumulation of soil on the outsoles. In particular, the disclosure relates to articles of footwear and components thereof including an outsole with an external hydrogel film that compositionally includes a crosslinked polymeric network having a plurality of copolymer chains with one or more hard segments physically crosslinked to other hard segments of the copolymer chains, and one or more hydrophilic soft segments covalently bonded to the hard segments. The outsoles can prevent or reduce the accumulation of soil on the footwear during wear on unpaved surfaces such as sporting fields. When the outsoles are wetted with water, the outsoles can become more compliant and/or can rapidly uptake and/or expel water, which can prevent soil from adhering to the outsole and/or can assist in shedding soil present on the outsole.
1. An outsole for an article of footwear, the outsole comprising:
an outsole backing member;
a film secured to the outsole backing member and defining an external surface of the outsole, wherein the film has a dry-state film thickness ranging from 0.1 millimeters to 5 millimeters, wherein the film comprises a crosslinked polymeric network, wherein the crosslinked polymeric network comprises crystalline regions and amorphous hydrophilic regions, wherein the crystalline regions are covalently bonded to the amorphous hydrophilic regions, and wherein the amorphous hydrophilic regions are present in the crosslinked polymeric network at a ratio of at least 20:1 by weight relative to the crystalline regions;
and a plurality of traction elements on the outsole backing member.
2. The outsole of claim 1 , wherein the amorphous hydrophilic regions are covalently bonded to the crystalline regions through carbamate linkages.
3. The outsole of claim 1 , wherein the film has a water uptake capacity at 24 hours ranging from 100% by weight to 700% by weight, as characterized by a Water Uptake Capacity Test with a Co-Extruded Film Sampling Procedure.
4. The outsole of claim 1 , wherein the crosslinked polymeric network is a physically crosslinked polymer network.
5. The outsole of claim 1 , wherein the crosslinked polymeric network includes carbamate linkages.
6. The outsole of claim 1 , wherein the amorphous hydrophilic regions are present in the hydrogel at a ratio ranging from 20:1 to 110:1 by weight relative to the crystalline regions.
7. The outsole of claim 6 , wherein the ratio of the amorphous hydrophilic regions to the crystalline regions ranges from 40:1 to 80:1.
8. The outsole of claim 1 , wherein each of the plurality of traction elements comprises a terminal edge, and wherein the film is not present on the terminal edges of any of the plurality of traction elements.
9. The outsole of claim 1 , wherein one or more of the traction elements is selected from the group consisting of: a cleat, a stud, a spike, and a lug.
10. The outsole of claim 1 , wherein the traction elements are integrally formed with the outsole backing member.
11. The outsole of claim 1 , wherein the traction elements are removable traction elements.
12. An article of footwear comprising:
an outsole substrate;
a plurality of traction elements operably secured to the outsole substrate;
an upper secured to the outsole substrate; and,
a film secured to the outsole substrate and defining an external surface of the outsole, wherein the film comprises a crosslinked polymeric network, wherein the crosslinked polymeric network comprises crystalline regions and amorphous hydrophilic regions, wherein the crystalline regions are covalently bonded to the amorphous hydrophilic regions, and wherein the amorphous hydrophilic regions are present in the crosslinked polymeric network at a ratio of at least 20:1 by weight relative to the crystalline regions.
13. The article of footwear of claim 12 , wherein the ratio of the amorphous hydrophilic regions to the crystalline regions ranges from 40:1 by weight to 110:1 by weight.
14. The article of footwear of claim 13 , wherein the ratio of the amorphous hydrophilic regions to the crystalline regions ranges from 60:1 by weight to 80:1 by weight.
15. The article of claim 12 , wherein the film exhibits a swell thickness increase at 1 hour greater than 50%, as characterized by a Swelling Capacity Test with a Co-Extruded Film Sampling Procedure.
16. The article of footwear of claim 12 , wherein the crosslinked polymeric network is a physically crosslinked polymer network.
17. The article of footwear of claim 12 , wherein the crosslinked polymeric network includes carbamate linkages.
18. The article of footwear of claim 12 , wherein the amorphous hydrophilic regions are present in the hydrogel at a ratio ranging from 20:1 to 110:1 by weight relative to the crystalline regions.
19. The article of footwear of claim 12 , wherein each of the plurality of traction elements comprises a terminal edge, and wherein the film is not present on the terminal edges of any of the plurality of traction elements.
20. The article of footwear of claim 12 , wherein one or more of the traction elements is selected from the group consisting of: a cleat, a stud, a spike, and a lug.
21. The article of footwear of claim 12 , wherein the traction elements are integrally formed with the outsole substrate.
22. The article of footwear of claim 12 , wherein the traction elements are removable traction elements.