Membrane separation device
The present application relates to a membrane separation device. According to the separation device of the present application, components to be separated using a separation membrane having a small area size can be separated with high selectivity and consequently processing efficiency and economical efficiency can be superbly improved; and according to a method for producing an expanded polystyrene which includes the membrane separation device, components to be separated using a separation membrane having a small area size, in particular, a volatile organic compound (VOC), can be separated with high selectivity and consequently processing efficiency and economical efficiency can be superbly improved, and also, by separating and recovering VOC, an effect in preventing environmental pollution caused by global warming is exhibited.
1. A membrane separation device comprising:
a first separation membrane, into which a feed stream flows, and in which the feed stream is divided into a first permeate stream which passes through the first separation membrane and a first non-permeate stream which does not pass through the first separation membrane and the first permeate stream and the first non-permeate stream are discharged;
a second separation membrane, into which the first non-permeate stream flows, and in which the first non-permeate stream is divided into a second permeate stream which passes through the second separation membrane and a second non-permeate stream which does not pass through the second separation membrane and the second permeate stream and the second non-permeate stream are discharged;
a gas-liquid separator coupled to a front end of the first separation membrane and/or coupled between the first separation membrane and the second separation membrane to divide the first permeate stream and the second permeate stream into a gas stream and a liquid stream, discharge the divided gas stream and allow the gas stream to flow into the first separation membrane and/or second separation membrane together with the feed stream or the first non-permeate stream, and
a decompression device that decompresses the first non-permeate stream,
wherein the gas-liquid separator is coupled so that the gas stream discharged from the gas-liquid separator flows into the second separation membrane together with the first non-permeate stream, and
wherein the first separation membrane and the second separation membrane have different selectivities and permeabilities with each other with respect to the at least two components.
2. The membrane separation device of claim 1 , wherein the first separation membrane and the second separation membrane satisfy the following Formulas 1 and 2:
α 1 AB −α 2 AB >0 [Formula 1]
P 2 A −P 1 A >0 [Formula 2]
wherein α 1 AB represents a selectivity (P 1 A /P 1 B ) of a component A to a component B present in the feed stream flowing into the first separation membrane,
α 2 AB represents a selectivity (P 2 A /P 2 B ) of the component A to the component B present in the first non-permeate stream flowing into the second separation membrane,
P 1 A and P 1 B represent permeabilities of the component A and the component B present in the feed stream flowing into the first separation membrane, respectively, and
P 2 A and P 2 B represent permeabilities of the component A and the component B present in the first non-permeate stream flowing into the second separation membrane, respectively,
wherein the component A represents a component to be separated from among components flowing into each separation membrane, and the component B represents the other component with the exception of the component A from among the components flowing into each separation membrane.
3. The membrane separation device of claim 2 , wherein the first separation membrane and the second separation membrane satisfy the following Formulas 3 and 4:
α 1 AB >1 [Formula 3]
α 2 AB >1 [Formula 4]
wherein α 1 AB and α 2 AB are as defined in claim 2 .
4. The membrane separation device of claim 1 , further comprising a pressure device configured to apply a pressure to the gas stream before the gas stream discharged from the gas-liquid separator flows into the first separation membrane and/or the second separation membrane.
5. An apparatus for producing an expandable polystyrene, comprising:
a reactor, and
the membrane separation device defined in claim 1 ,
wherein the reactor is filled with an expandable gas and a portion of the expandable gas is impregnated in polystyrene beads in the reactor,
wherein the membrane separation device separates an unimpregnated expandable gas discharged from the reactor.
6. A membrane separation device comprising:
a condenser in which a feed stream including at least two components flows;
a first separation membrane, into which an uncondensed stream from the condenser flows, and in which the uncondensed stream is divided into a first permeate stream which passes through the first separation membrane and a first non-permeate stream which does not pass through the first separation membrane and the first permeate stream and the first non-permeate stream are discharged;
a second separation membrane into which the first non-permeate stream flows, and in which the first non-permeate stream is divided into a second permeate stream which passes through the second separation membrane and a second non-permeate stream which does not pass through the second separation membrane and the second permeate stream and the second non-permeate stream are discharged; and
a gas-liquid separator coupled to a front end of the first separation membrane and/or coupled between the first separation membrane and the second separation membrane to divide the first permeate stream and the second permeate stream into a gas stream and a liquid stream, discharge the divided gas stream and allow the gas stream to flow into the first separation membrane and/or second separation membrane together with the feed stream or the first non-permeate stream; and
a decompression device that decompresses the first non-permeate stream,
wherein the gas-liquid separator is coupled so that the gas stream discharged from the gas-liquid separator flows into the second separation membrane together with the first non-permeate stream, and
wherein the first separation membrane and the second separation membrane have different selectivities and permeabilities with each other with respect to the at least two components.
7. The membrane separation device of claim 6 , wherein the first separation membrane and the second separation membrane satisfy the following Formulas 1 and 2:
α 1 AB −α 2 AB >0 [Formula 1]
P 2 A −P 1 A >0 [Formula 2]
wherein α 1 AB represents a selectivity (P 1 A /P 1 B ) of a component A to a component B present in the uncondensed stream flowing into the first separation membrane,
α 2 AB represents a selectivity (P 2 A /P 2 B ) of the component A to the component B present in the first non-permeate stream flowing into the second separation membrane,
P 1 A and P 1 B represent permeabilities of the component A and the component B present in the uncondensed stream flowing into the first separation membrane, respectively, and
P 2 A and P 2 B represent permeabilities of the component A and the component B present in the first non-permeate stream flowing into the second separation membrane, respectively,
wherein the component A represents a component to be separated from among components flowing into each separation membrane, and the component B represents the other component with the exception of the component A from among the components flowing into each separation membrane.
8. The membrane separation device of claim 7 , wherein the first separation membrane and the second separation membrane satisfy the following Formulas 3 and 4:
α 1 AB >1 [Formula 3]
α 2 AB >1 [Formula 4]
wherein α 1 AB and α 2 AB are as defined in claim 7 .
9. The membrane separation device of claim 6 , further comprising a pressure device configured to apply a pressure to the gas stream before the gas stream discharged from the gas-liquid separator flows into the first separation membrane and/or the second separation membrane.