Geopolymer with nanoparticle retardant and method
A method of controlling the setting time of a geopolymer by coating aluminosilicate particles with nanoparticles to slow the geopolymerization reaction. The coating effectiveness of the nanoparticles may be enhanced by pretreating the aluminosilicate particles with a layer-by-layer assembly of polyelectrolytes. A geopolymer is formed by mixing about 39% to about 66% by weight aluminosilicate source, about 0% to about 40% by weight sand, about 19% to about 33% by weight of alkali activator solution, and about 1% to about 4% nanoparticles.
1. A composition of matter formed by the mixing of components comprising:
about 39% to about 66% by weight aluminosilicate source;
about 0% to about 40% by weight sand;
about 19% to about 33% by weight alkali activator solution; and
about 1% to about 4% by weight nanoparticle retardant.
2. The composition of matter of claim 1 , wherein the aluminosilicate source comprises fly ash, metakaolin, or rice husk.
3. The composition of matter of claim 1 , wherein the alkali activator solution comprises sodium silicate and a sodium hydroxide solution.
4. The composition of matter of claim 3 , wherein a concentration of the sodium hydroxide solution is in the range of about 10M to about 14M.
5. The composition of matter of claim 3 , wherein the alkali activator solution comprises a silicate to hydroxide ratio of about 1.5.
6. The composition of matter of claim 1 , wherein the nanoparticle retardant comprises halloysite nanotubes or kaolin nanoclay particles.
7. The composition of matter of claim 1 , wherein the composition is formed by mixing of components comprising:
about 64% to about 66% by weight aluminosilicate source;
about 32% to about 33% by weight alkali activator solution; and
about 1% to about 4% by weight nanoparticle retardant.
8. The composition of matter of claim 1 , wherein the composition is formed by mixing of components comprising:
about 39% to about 40% by weight aluminosilicate source;
about 39% to about 40% by weight sand;
about 19% to about 20% by weight alkali activator solution; and
about 1% to about 3% by weight nanoparticle retardant.
9. The composition of matter of claim 1 , wherein a setting time of the composition is about 47 minutes to about 205 minutes.
10. The composition of matter of claim 9 , wherein the compressive strength of the composition 24 hours after mixing is about 4,000 psi to about 8,600 psi.
11. The composition of matter of claim 1 , wherein the flowability of the composition is about 59 to about 116.