Wavelength conversion member including phosphor that converts light from semiconductor light-emitting element into longer-wavelength light
A wavelength conversion member, comprises: a substrate; a first wavelength conversion layer on the substrate, the first wavelength conversion layer containing a first phosphor and a first matrix; and a second wavelength conversion layer containing a second phosphor, first inorganic particles, and a second matrix. The first phosphor and the second phosphor convert at least part of the excitation light incident on the second main surface into first light having longer wavelengths than the excitation light. The first light is emitted from the second main surface of the second wavelength conversion layer. A volume Vp1 of the first phosphor, a volume Vw1 of the first wavelength conversion layer, a volume Vp2 of the second phosphor, and a volume Vw2 of the second wavelength conversion layer satisfy Vp1/Vw1>Vp2/Vw2.
1. A wavelength conversion member, comprising:
a substrate;
a first wavelength conversion layer on the substrate, the first wavelength conversion layer containing a first phosphor and a first matrix; and
a second wavelength conversion layer having: a first main surface facing the first wavelength conversion layer; and a second main surface on which excitation light from a semiconductor light-emitting element is incident, the second wavelength conversion layer containing a second phosphor, first inorganic particles, and a second matrix, wherein
the first phosphor and the second phosphor convert at least part of the excitation light incident on the second main surface into first light having longer wavelengths than the excitation light,
the first light is emitted from the second main surface of the second wavelength conversion layer, and
a volume Vp1 of the first phosphor, a volume Vw1 of the first wavelength conversion layer, a volume Vp2 of the second phosphor, and a volume Vw2 of the second wavelength conversion layer satisfy Vp1/Vw1>Vp2/Vw2.
2. The wavelength conversion member according to claim 1 , further comprising:
a reflective layer on at least one side face of the second wavelength conversion layer, the reflective layer containing:
second inorganic particles; and
a third matrix.
3. The wavelength conversion member according to claim 1 , wherein the volume Vp1 of the first phosphor is equal to or more than 30% and less than or equal to 80% of the volume Vw1 of the first wavelength conversion layer.
4. The wavelength conversion member according to claim 1 , wherein the volume Vp2 of the second phosphor is equal to or more than 0.1% and less than or equal to 20% of the volume Vw2 of the second wavelength conversion layer.
5. The wavelength conversion member according to claim 1 , wherein the first matrix has a higher thermal conductivity than the second matrix.
6. The wavelength conversion member according to claim 1 , wherein the first matrix is zinc oxide.
7. The wavelength conversion member according to claim 1 , wherein the second matrix is a material having a siloxane bond.
8. A light source, comprising:
a semiconductor light-emitting element that emits excitation light having a peak wavelength of 420 nm or more and 470 nm or less; and
a wavelength conversion member including:
a substrate;
a first wavelength conversion layer on the substrate, the first wavelength conversion layer containing a first phosphor and a first matrix; and
a second wavelength conversion layer having: a first main surface facing the first wavelength conversion layer; and a second main surface on which excitation light from a semiconductor light-emitting element is incident, the second wavelength conversion layer containing a second phosphor, first inorganic particles, and a second matrix, wherein
the first phosphor and the second phosphor convert at least part of the excitation light incident on the second main surface into first light having longer wavelengths than the excitation light,
the first light is emitted from the second main surface of the second wavelength conversion layer, and
a volume Vp1 of the first phosphor, a volume Vw1 of the first wavelength conversion layer, a volume Vp2 of the second phosphor, and a volume Vw2 of the second wavelength conversion layer satisfy Vp1/Vw1>Vp2/Vw2.
9. The light source according to claim 8 , further comprising:
a reflective layer on at least one side face of the second wavelength conversion layer, the reflective layer containing:
second inorganic particles; and
a third matrix.
10. The light source according to claim 8 , wherein the volume Vp1 of the first phosphor is equal to or more than 30% and less than or equal to 80% of the volume Vw1 of the first wavelength conversion layer.
11. The light source according to claim 8 , wherein the volume Vp2 of the second phosphor is equal to or more than 0.1% and less than or equal to 20% of the volume Vw2 of the second wavelength conversion layer.
12. The light source according to claim 8 , wherein the first matrix has a higher thermal conductivity than the second matrix.
13. The light source according to claim 8 , wherein the first matrix is zinc oxide.
14. The light source according to claim 8 , wherein the second matrix is a material having a siloxane bond.
15. A vehicle headlamp, comprising:
a light source including a wavelength conversion member and a semiconductor light-emitting element that emits excitation light having a peak wavelength of 420 nm or more and 470 nm or less; and
an exit optical system that guides light from the light source to the outside,
the wavelength conversion member including:
a substrate;
a first wavelength conversion layer on the substrate, the first wavelength conversion layer containing a first phosphor, and a first matrix; and
a second wavelength conversion layer having: a first main surface facing the first wavelength conversion layer; and a second main surface on which excitation light from a semiconductor light-emitting element is incident, the second wavelength conversion layer containing a second phosphor, first inorganic particles, and a second matrix, wherein
the first phosphor and the second phosphor converting at least part of the excitation light incident on the second main surface into first light having longer wavelengths than the excitation light,
the first light is emitted from the second main surface of the second wavelength conversion layer, and
a volume Vp1 of the first phosphor, a volume Vw1 of the first wavelength conversion layer, a volume Vp2 of the second phosphor, and a volume Vw2 of the second wavelength conversion layer satisfy Vp1/Vw1>Vp2/Vw2.
16. The vehicle headlamp according to claim 15 , further comprising:
a reflective layer on at least one side face of the second wavelength conversion layer, the reflective layer containing:
second inorganic particles; and
a third matrix.
17. The vehicle headlamp according to claim 15 , wherein the volume Vp1 of the first phosphor is equal to or more than 30% and less than or equal to 80% of the volume Vw1 of the first wavelength conversion layer.
18. The vehicle headlamp according to claim 15 , wherein the volume Vp2 of the second phosphor is equal to or more than 0.1% and less than or equal to 20% of the volume Vw2 of the second wavelength conversion layer.
19. The vehicle headlamp according to claim 15 , wherein the first matrix has a higher thermal conductivity than the second matrix.
20. The vehicle headlamp according to claim 15 , wherein the first matrix is zinc oxide.