Low water metal ion dentifrice
A dentifrice composition having a low water phase comprising effective amounts of polyphosphate and ionic active ingredients. The composition comprises a source of metal ions, an inorganic phosphate salt having four or more phosphorus atoms and a cross-linked polyvinylpyrrolidone thickening agent in a single phase. Preferred metal ions are stannous, copper and zinc, in particular from zinc citrate and stannous fluoride.
1. A low water dentifrice composition comprising in a single phase:
a source of metal ions;
at least one polyphosphate salt selected from the group consisting of inorganic polyphosphate salts which have four or more phosphorous atoms; and
a thickening agent comprising a cross-linked polyvinylpyrrolidone;
wherein the dentifrice composition is a paste or gel, wherein the dentifrice composition has a total water content of 3% to 10% based on the weight of the composition, and wherein the at least one polyphosphate salt comprises from 1 to 10 wt % of the composition; and
wherein the source of metal ions comprises zinc citrate and stannous fluoride present in a combined amount of from 0.45 to 5% by weight of the composition;
wherein the cross-linked polyvinylpyrrolidone is present in an amount of 0.05 to 15% by weight of the composition;
wherein the composition does not comprise a peroxide source, and does not comprise a pyrophosphate or tripolyphosphate.
2. The composition of claim 1 , wherein the thickening agent consists essentially of a cross-linked polyvinylpyrrolidone.
3. The composition of claim 1 , wherein the at least one polyphosphate is an alkali metal salt of a hexametaphosphate.
4. The composition of claim 3 , wherein the at least one polyphosphate is sodium hexametaphosphate.
5. The composition of claim 1 , wherein the at least one polyphosphate salt comprises from 3 to 7 wt % of the composition.
6. The composition of claim 1 , wherein the dentifrice composition has a total water content of 3% to 4% based on the weight of the composition.
7. The composition of claim 1 , further comprising an aqueous buffer system for the source of metal ions.
8. The composition of claim 7 , wherein the buffer system is adapted to chelate the metal ions in the composition.
9. The composition of claim 8 , wherein the buffer system comprises at least one of an organic acid or an alkali metal salt thereof.
10. The composition of claim 9 , wherein the organic acid is citric acid.
11. The composition of claim 9 , wherein the buffer system comprises a mixture of citric acid and trisodium citrate.
12. The composition of claim 9 , wherein the buffer system comprises from 0.1 to 10 wt % of the composition.
13. The composition of claim 9 , wherein the buffer system is present, by weight, in an amount which is greater than the amount, by weight, of the source of metal ions.
14. The composition of claim 1 , wherein the at least one polyphosphate is an alkali metal salt of a tetraphosphate.