Surface-treated powder and cosmetic having the same
Provided is a surface-treated powder, where at least one compound of general formula (1) adheres to the surface of the powder. In formula (1), R 2 is a monovalent aromatic hydrocarbon group having 6-12 carbon atoms, R 4 is a monovalent non-aromatic hydrocarbon group having 1-30 carbon atoms, R 1 and R 0 are a group selected from aforementioned groups defined for R 2 and R 4 , and R 3 is a group of formula (2), R 5 is a divalent hydrocarbon group having 2 to 8 carbon atoms and R 6 is an alkyl group having 1 to 6 carbon atoms, a, b, c, and d are integers of from 0-3, 0-200, 1-150, and 0-50, respectively, provided that when a is 0, d and e are integers of from 1-50 and 0-2, respectively, and c/(b+c+d) is 0.25 or more.
1. A surface-treated powder, wherein at least one compound represented by the following general formula (1) adheres to the surface of the powder,
wherein R 2 is, independently of each other, a monovalent aromatic hydrocarbon group having 6 to 12 carbon atoms, R 4 is, independently of each other, a substituted or unsubstituted, monovalent non-aromatic hydrocarbon group having 1 to 30 carbon atoms, R 1 and R 0 are, independently of each other, a group selected from aforementioned groups defined for R 2 and R 4 , and R 3 is, independently of each other, a group represented by the following formula (2):
wherein R 0 is as defined above, R 5 is a divalent hydrocarbon group having 2 to 8 carbon atoms and R 6 is an alkyl group having 1 to 6 carbon atoms,
a is an integer of from 0 to 3, b is an integer of from 0 to 200, c is an integer of from 1 to 150, d is an integer of from 0 to 50, provided that when a is 0, d is an integer of from 1 to 50, e is an integer of from 0 to 2 and c/(b+c+d) is 0.25 or more, and the compound may or may not be a block copolymer.
2. The surface-treated powder according to claim 1 , wherein the powder is at least one selected from the group consisting of powder of a surfactant metal salt, colored pigments, pearl pigments, metal powder pigments, natural colorants and other inorganic or organic powder.
3. The surface-treated powder according to claim 2 , wherein the powder is zinc oxide, titanic oxide, or an extender pigment selected from the group consisting of mica, sericite, talc, and kaolin.
4. A cosmetic comprising (A) the surface-treated powder according to claim 1 , and (B) oil.
5. The cosmetic according to claim 4 , wherein component (B) comprises oil having an inorganic/organic balance (IOB) of 0.05 to 1.
6. The cosmetic according to claim 5 , wherein the oil is a silicone oil.
7. The cosmetic according to claim 4 , wherein component (B) is a mixture of the silicone oil and a polar oil other than the silicone oil having an IOB of 0.05 to 1.
8. The cosmetic according to claim 4 , further comprising an organo ultraviolet absorbent.
9. The cosmetic according to claim 4 , further comprising a silicone surfactant represented by the following general formula (3):
wherein R is, independently of each other, a substituted or unsubstituted, monovalent hydrocarbon group having 1 to 30 carbon atoms, and R 7 is, independently of each other, represented by the following formula (4) or (5), wherein an oxyethylene unit or an oxypropylene unit in the following formula (4) may or may not be a block copolymer, and a glycerin residue in the following formula (5) may have a branched structure to constitute an isomer,
—C p H 2p O(C 2 H 4 O) q (C 3 H 6 O) m R 9 (4)
—C p H 2p O(C 3 H 5 (OR 10 )O) n R 11 (5)
wherein R 8 is a monovalent hydrocarbon group having 6 to 30 carbon atoms, R 9 , R 10 and R 11 are, independently of each other, a hydrogen atom or a monovalent hydrocarbon group having 1 to 6 carbon atoms, and at least one of R 10 and R 11 is a hydrogen atom, f is an integer of from 0 to 200, g is an integer of from 1 to 30, h is an integer of from 0 to 50, i is an integer of from 0 to 30, p is an integer of from 1 to 6, k is an integer of from 0 to 100, q is an integer of from 0 to 50, m is an integer of from 0 to 50, provided that a total of q and m is 1 or more, and n is an integer of from 1 to 6.
10. The cosmetic according to claim 4 , further comprising an acryl-silicone graft copolymer.
11. The cosmetic according to claim 4 , wherein the cosmetic is any one of skin-care cosmetics, makeup cosmetics, hair cosmetics, antiperspirant cosmetics, and ultraviolet protectants.
12. The cosmetic according to claim 4 , wherein the cosmetic is a water-in-oil type emulsion, an oil-in-water type emulsion, a nonaqueous cosmetic or a powder cosmetic.
13. The surface-treated powder according to claim 2 , wherein the natural colorants are selected from the group consisting of carminic acid, laccaic acid, carthamin, brazilin, and crocin.