Composite material with thermoplastic toughened novolac-based epoxy resin matrix
Pre-impregnated composite material (prepreg) that can be cured/molded to form aerospace composite parts. The prepreg includes carbon reinforcing fibers and an uncured resin matrix. The resin matrix includes an epoxy component that is a combination of a hydrocarbon epoxy novolac resin and a trifunctional epoxy resin and optionally a tetrafunctional epoxy resin. The resin matrix includes polyethersulfone as a toughening agent and a thermoplastic particle component.
1. A pre-impregnated composite material comprising:
A) reinforcing fibers comprising carbon fibers; and
B) an uncured resin matrix comprising:
a) an epoxy resin component comprising from 7 to 27 weight percent of a hydrocarbon epoxy novolac resin, based on the total weight of said uncured resin matrix, and from 26 to 36 weight percent of triglycidyl meta-aminophenol;
b) 11 to 19 weight percent of a thermoplastic particle component based on the total weight of said uncured resin matrix, said thermoplastic component comprising thermoplastic particles that comprise a polyamide which is the polymeric condensation product of 1,10-decane dicarboxylic acid and an amine component having the formula
where both R 2 are hydrogen and both R 1 are methyl or hydrogen;
c) 7 to 12 weight percent of a thermoplastic toughening agent, based on the total weight of said uncured resin matrix, said thermoplastic toughening agent comprising polyethersulfone; and
d) 17 to 27 weight percent of a curing agent, based on the total weight of said uncured resin matrix, said curing agent comprising 4,4′-diaminodiphenyl sulphone and/or 3,3′-diaminodiphenyl sulphone.
2. The pre-impregnated composite material according to claim 1 wherein said reinforcing fibers comprise a plurality of carbon fiber tow which each comprises from 10,000 to 14,000 carbon filaments wherein the weight per length of each of said carbon tows is from 0.2 to 0.6 grams per meter and wherein the tensile strength of each of said carbon tows is from 750 to 860 kilopounds per square inch and the tensile modulus of each of said carbon tows is from 35 to 45 megapounds per square inch.
3. The pre-impregnated composite material according to claim 1 wherein said curing agent is 4,4′-diaminodiphenyl sulphone.
4. The composite part or structure that has been formed by curing a pre-impregnated composite material according to claim 1 .
5. The composite part or structure according to claim 4 wherein said composite part or structure forms at least part of an aircraft primary structure.
6. The pre-impregnated composite material according to claim 1 wherein both R 2 are hydrogen and both R 1 are methyl.
7. A method for making a pre-impregnated composite material that is curable to form a composite part, said method comprising the steps of:
A) providing reinforcing fibers comprising carbon fibers; and
B) impregnating said reinforcing fibers with an uncured resin matrix wherein said uncured resin matrix comprises:
a) an epoxy resin component comprising from 7 to 27 weight percent of a hydrocarbon epoxy novolac resin, based on the total weight of said uncured resin matrix, and from 26 to 36 weight percent of triglycidyl meta-aminophenol;
b) 11 to 19 weight percent of a thermoplastic particle component based or the total weight of said uncured resin matrix, said thermoplastic component comprising thermoplastic particles that comprise a polyamide which is the polymeric condensation product of 1,10-decane dicarboxylic acid and an amine component having the formula
where both R 2 are hydrogen and both R 1 are methyl or hydrogen;
c) 7 to 12 weight percent of a thermoplastic toughening agent, based on the total weight of said uncured resin matrix, said thermoplastic toughening agent comprising polyethersulfone; and
d) 17 to 27 weight percent of a curing agent, based on the total weight of said uncured resin matrix, said curing agent comprising 4,4′-diaminodiphenyl sulphone and/or 3,3′-diaminodiphenyl sulphone.
8. The method for making a composite part or structure comprising the steps of providing a pre-impregnated composite material according to claim 1 and curing said pre-impregnated composite material.
9. The method for making a pre-impregnated composite material that is curable to form a composite part according to claim 7 wherein said reinforcing fibers comprise a plurality of carbon fiber tow which each comprises from 10,000 to 14,000 carbon filaments wherein the weight per length of each of said carbon tows is from 0.2 to 0.6 grams per meter and wherein the tensile strength of each of said carbon tows is from 750 to 860 kilopounds per square inch and the tensile modulus of each of said carbon tows is from 35 to 45 megapounds per square inch.
10. The method for making a pre-impregnated composite material that is curable to form a composite part according to claim 7 wherein said curing agent is 4,4′-diaminodiphenyl sulphone.
11. The method for making a composite part or structure which includes the step of curing the pre-impregnated composite material according to claim 1 .
12. The method for making a pre-impregnated composite material that is curable to form a composite part according to claim 7 wherein both R 2 are hydrogen and both R 1 are methyl.