Composite with improved mechanical properties and molded article including the same
The present invention provides a composite obtained by processing a resin composition including a thermoplastic resin, multi-walled carbon nanotubes, and a reinforcing material. The multi-walled carbon nanotubes have an average diameter of 10 nm or more and an I d /I g of 1 or less. The walls of the multi-walled carbon nanotubes consist of 10 or more layers of graphene. The rate of residual length of the carbon nanotubes present in the composite is 40% or more. The composite has improved mechanical properties without deterioration of conductivity. Due to these advantages, the composite can be used to manufacture various molded articles.
1. A composite obtained by processing a resin composition comprising a thermoplastic resin, multi-walled carbon nanotubes, and a reinforcing material,
wherein the average diameter of the multi-walled carbon nanotubes is 10 nm-30 nm, walls of the multi-walled carbon nanotubes have 10-50 layers of graphene, an I d /I g of the multi-walled carbon nanotubes is 0.6-1.0, and
the rate of residual length of the multi-walled carbon nanotubes present in the composite is 40%-99%, the rate of residual length being defined by Equation 1:
Rate of residual length (%)=(Content of ≥500 nm long multi-walled carbon nanotubes in the composite)/(Content of all multi-walled carbon nanotubes in the composite)×100.
2. The composite according to claim 1 , wherein the composite has a tensile strength of 83 MPa or more.
3. The composite according to claim 1 , wherein the composite has a tensile modulus of 3.3 GPa or more.
4. The composite according to claim 1 , wherein the composite has a surface resistivity of 1.0×10 9 Ω/sq. or less.
5. The composite according to claim 1 , wherein the multi-walled carbon nanotubes are of a bundle type or non-bundle type.
6. The composite according to claim 1 , wherein the multi-walled carbon nanotubes are present in an amount of 0.1 to 10 parts by weight, based on 100 parts by weight of the thermoplastic resin.
7. The composite according to claim 1 , wherein the multi-walled carbon nanotubes present in the composite have an average length of 0.5 μm to 50 μm.
8. The composite according to claim 1 , wherein the reinforcing material has a fibrous shape.
9. The composite according to claim 1 , wherein the reinforcing material is selected from carbon fibers, glass fibers, milled glass fibers, aramid fibers, alumina fibers, silicon carbide fibers, ceramic fibers, asbestos fibers, gypsum fibers, metal fibers, and mixtures thereof.
10. The composite according to claim 1 , wherein the reinforcing material is present in an amount of 0.1 to 50 parts by weight, based on 100 parts by weight of the thermoplastic resin.
11. The composite according to claim 1 , further comprising a carbonaceous conductive additive.
12. The composite according to claim 11 , wherein the carbonaceous conductive additive is selected from carbon black, graphene, fullerenes, and carbon nanofibers.
13. The composite according to claim 11 , wherein the carbonaceous conductive additive is present in an amount of 0.1 to 30 parts by weight, based on 100 parts by weight of the thermoplastic resin.
14. The composite according to claim 1 , wherein the processing is extrusion.
15. The composite according to claim 1 , wherein the I d /I g of the multi-walled carbon nanotubes is 0.6-0.8.
16. The composite according to claim 15 , wherein the rate of residual length is at least 59%.
17. The composite according to claim 1 , wherein the multi-walled carbon nanotubes present in the composite have an average length of 0.5 μm to 1.25 μm.
18. A molded article comprising the composite according to claim 1 .
19. The molded article according to claim 18 , wherein the processing is extrusion, injection molding or a combination thereof.
20. The molded article according to claim 18 , wherein the molded article is an antistatic article, an electrical/electronic product housing or an electrical/electronic part.