Process for the production of a thermally conductive article
The present disclosure relates to a process for the production of a thermally conductive article that includes (1) pleating a thermally anisotropic sheet having a thermal conductivity in a first plane that is higher than the thermal conductivity in a second plane perpendicular to the first plane and (2) compacting the pleated structure. An article obtained by the process, the use of the thermally conductive article for production of a device, and the device are also disclosed.
1. A process for the production of a thermally conductive article, said process comprising:
pleating at least one thermally anisotropic sheet having a first thermal conductivity in a first plane which is higher than a second thermal conductivity in a second plane that is perpendicular to the first plane to form a pleated structure, said pleated structure comprises a plurality of pleats, each said pleat having a first surface and a second surface; and
compacting the pleated structure so that said first and second surfaces which face each other due to the formation of said pleats are at least partially brought into direct contact with each other, said pleated structure having an upper surface and a lower surface,
wherein the thermally anisotropic sheet includes at least one thermally anisotropic polymer layer.
2. The process according to claim 1 , further comprising bonding said pleats of at least one of said first and second surfaces to each other.
3. The process according to claim 1 , wherein said sheet comprises a plurality of thermally anisotropic expanded polytetrafluoroethylene layers.
4. The process according to claim 1 , further comprising bonding a film to at least one of the upper surface and the lower surface of the pleated structure.
5. The process according to claim 1 , wherein the sheet is treated with a thermal interphase wax.
6. The process according to claim 1 , wherein the pleated structure comprises pleats having a pleat height, and
wherein said pleat height in relation to the sheet thickness is from 1000:1 to 2:1.
7. The process according to claim 1 , wherein the pleats having a pleat height, and
wherein said sheet is pleated so that in the pleated structure comprises pleats with different pleat heights.
8. The process according to claim 1 , wherein the thermally anisotropic sheet has a thickness from 1 μm to 500 μm.
9. The process according to claim 1 , wherein said pleating of the sheet is performed perpendicular to the direction of maximum thermal conductivity.
10. The process according to claim 1 , wherein the thermally anisotropic sheet further comprises a layer of a thermally isotropic conductive material.
11. The process according to claim 1 , wherein the thermally anisotropic sheet comprises a thermally anisotropic polymer layer.
12. The process according to claim 11 , wherein the thermally anisotropic polymer layer comprises a polyolefin or a fluoropolymer.
13. The process according to claim 12 , wherein the thermally anisotropic polymer layer comprises a polyethylene.
14. The process according to claim 12 , wherein the thermally anisotropic polymer layer comprises a fluoropolymer selected from polytetrafluoroethylene, a modified polytetrafluoroethylene, a fluorothermoplastic, a fluoroelastomer and combinations thereof.
15. The process according to claim 1 , wherein the intrinsic thermal conductivity of the thermally anisotropic sheet is 0.5 W/mK or more in the direction of maximum intrinsic thermal conductivity.
16. The process of claim 1 , wherein said sheet is a composite sheet comprising a layer of a thermally anisotropic expanded polytetrafluoroethylene attached to a metallic film.
17. The process of claim 16 , wherein said composite sheet further comprises an adhesive layer on one or both of an upper side and a lower surface of said composite sheet.
18. A process for the production of a thermally conductive article, said process comprising:
pleating at least one thermally anisotropic sheet having a first thermal conductivity in a first plane which is higher than a second thermal conductivity in a second plane that is perpendicular to the first plane to form a pleated structure;
compacting the pleated structure, said pleated structure having an upper surface and a lower surface, and
bonding a film to at least one of the upper surface and the lower surface of the pleated structure,
wherein the pleated structure comprises a plurality of pleats, said pleats having a first surface and a second surface.
19. A process for the production of a thermally conductive article, said process comprising:
pleating at least one thermally anisotropic sheet having a first thermal conductivity in a first plane which is higher than a second thermal conductivity in a second plane that is perpendicular to the first plane to form a pleated structure; and
compacting the pleated structure, said pleated structure having an upper surface and a lower surface,
wherein the pleated structure comprises a plurality of pleats, said pleats having a first surface and a second surface, and
wherein the sheet is treated with a thermal interphase wax.
20. A process for the production of a thermally conductive article, said process comprising:
pleating at least one thermally anisotropic sheet having a first thermal conductivity in a first plane which is higher than a second thermal conductivity in a second plane that is perpendicular to the first plane to form a pleated structure; and
compacting the pleated structure, said pleated structure having an upper surface and a lower surface,
wherein the pleated structure comprises a plurality of pleats, said pleats having a first surface and a second surface, and
wherein the at least one thermally anisotropic sheet comprises a thermally anisotropic polymer layer.
21. The process according to claim 20 , wherein the thermally anisotropic polymer layer comprises a polyolefin or a fluoropolymer.
22. The process according to claim 21 , wherein the thermally anisotropic polymer layer comprises a polyethylene.
23. The process according to claim 21 , wherein the thermally anisotropic polymer layer comprises a fluoropolymer selected from polytetrafluoroethylene, a modified polytetrafluoroethylene, a fluorothermoplastic, a fluoroelastomer and combinations thereof.
24. The process according to claim 20 , further comprising bonding said pleats of at least one of said first and second surfaces to each other.
25. The process according to claim 20 , wherein said at least one thermally anisotropic sheet comprises a plurality of thermally anisotropic expanded polytetrafluoroethylene layers.
26. The process according to claim 20 , further comprising bonding a film to at least one of the upper surface and the lower surface of the pleated structure.
27. The process according to claim 20 , wherein the at least one thermally anisotropic sheet is treated with a thermal interphase wax.
28. The process according to claim 20 , wherein the pleated structure comprises pleats having a pleat height, and
wherein said pleat height in relation to a sheet thickness is from 1000:1 to 2:1.
29. The process according to claim 20 , wherein the pleats having a pleat height, and
wherein said sheet is pleated so that in the pleated structure comprises pleats with different pleat heights.
30. A process for the production of a thermally conductive article, said process comprising:
pleating at least one thermally anisotropic sheet having a first thermal conductivity in a first plane which is higher than a second thermal conductivity in a second plane that is perpendicular to the first plane to form a pleated structure; and
compacting the pleated structure, said pleated structure having an upper surface and a lower surface,
wherein the pleated structure comprises a plurality of pleats, said pleats having a first surface and a second surface,
wherein said at least one thermally anisotropic sheet is a composite sheet comprising a layer of a thermally anisotropic expanded polytetrafluoroethylene attached to a metallic film.
31. The process of claim 30 , wherein said composite sheet further comprises an adhesive layer on one or both of an upper side and a lower surface of said composite sheet.