Separator for a non-aqueous secondary battery and non-aqueous secondary battery
The present invention provides a separator for a non-aqueous secondary battery including a porous substrate, and an adhesive porous layer that is formed at one or both sides of the porous substrate, that contains polyvinylidene fluoride resin A and polyvinylidene fluoride resin B, and that has a porosity of from 30% to 60% and an average pore size of from 20 nm to 100 nm.
1. A separator for a non-aqueous secondary battery, comprising:
a porous substrate, and
an adhesive porous layer that is coated on one side or both sides of the porous substrate, contains (1) the following polyvinylidene fluoride resin A and (2) the following polyvinylidene fluoride resin B, and has a porosity of from 30% to 52% and an average pore size of from 36 nm to 100 nm:
(1) polyvinylidene fluoride resin A selected from the group consisting of vinylidene fluoride homopolymers, and vinylidene fluoride copolymers containing structural units derived from vinylidene fluoride and structural units derived from hexafluoropropylene, a total content of structural unit derived from hexafluoropropylene in each of the vinylidene fluoride copolymers being 1.5 mol % or less of a total content of structural unit in each of the vinylidene fluoride copolymers; and
(2) polyvinylidene fluoride resin B selected from the group consisting of vinylidene fluoride copolymers containing a structural unit derived from vinylidene fluoride and a structural unit derived from hexafluoropropylene, a total content of structural unit derived from hexafluoropropylene in each of the vinylidene fluoride copolymers being greater than 1.5 mol % of a total content of structural unit in each of the vinylidene fluoride copolymers,
wherein, in the adhesive porous layer, a content of the polyvinylidene fluoride resin A is from 15 parts by mass to 40 parts by mass, and a content of the polyvinylidene fluoride resin B from 60 parts by mass to 85 parts by mass, when a total amount of the polyvinylidene fluoride resin A and the polyvinylidene fluoride resin B is taken as 100 parts by mass.
2. The separator for a non-aqueous secondary battery according to claim 1 , wherein the adhesive porous layer has an average pore size of from 36 nm to 70 nm.
3. The separator for a non-aqueous secondary battery according to claim 1 , wherein an amount per unit area of the adhesive porous layer at one side of the porous substrate is from 0.5 g/m 2 to 1.5 g/m 2 .
4. The separator for a non-aqueous secondary battery according to claim 1 , wherein the value obtained by subtracting the Gurley value of the porous substrate from the Gurley value of the separator provided with an adhesive porous layer is 300 sec/100 cc or less.
5. The separator for a non-aqueous secondary battery according to claim 1 , wherein the polyvinylidene fluoride resin A consists of structural units derived from vinylidene fluoride and structural units derived from hexafluoropropylene, and the polyvinylidene fluoride resin B consists of a structural unit derived from vinylidene fluoride and a structural unit derived from hexafluoropropylene.
6. The separator for a non-aqueous secondary battery according to claim 1 , wherein
the polyvinylidene fluoride resin A and the polyvinylidene fluoride resin B are bound together to form a porous structure by being dissolved and blended together in a state in which the polyvinylidene fluoride resin A and the polyvinylidene fluoride resin B are in a solvent.
7. A non-aqueous secondary battery comprising a positive electrode, a negative electrode, and the separator for a non-aqueous secondary battery according to claim 1 , the separator being disposed between the positive electrode and the negative electrode, wherein, in the non-aqueous secondary battery, electromotive force is obtained by lithium doping/dedoping.