Scintillator and method for manufacturing the same
The present invention relates to a scintillator, a method for manufacturing the same, and an application for the same. The scintillator according to an embodiment of the present invention includes a matrix material including, as a main component, thallium, lanthanum, and a halogen element; and an activator doped onto the matrix material. The scintillator according to an embodiment of the present invention has a formula TlaLabXc:yCe, and in the formula: X is a halogen element; a=1, b=2, c=7, or a=2, b=1, c=5, or a=3, b=1, c=6; and y>0 and y≤0.5. The scintillator according to an embodiment of the present invention has a high efficiency of detecting radiations, a greater light yield, and an excellent fluorescence decay time characteristic.
1. A scintillator comprising:
a matrix material comprising thallium, lanthanum, and a halogen element; and
an activator doped to the matrix material.
2. The scintillator of claim 1 , wherein the activator comprises cerium.
3. The scintillator of claim 2 , wherein a formula thereof is TlaLabXc:yCe, and in the formula: X is a halogen element; a=1, b=2, c=7, or a=2, b=1, c=5, or a=3, b=1, c=6; and y>0 and y≤0.5.
4. The scintillator of claim 1 , wherein the halogen element comprises at least one among Cl, Br and I.
5. The scintillator of claim 1 wherein the matrix material does not comprise an alkali element.
6. A scintillator comprising a matrix material doped with an activator, the matrix material comprising a thallium halide and a lanthanum halide,
wherein the matrix material comprises a material having a formula TlaLabXc, and in the formula, X is a halogen element; and a=1, b=2, c=7, or a=2, b=1, c=5, or a=3, b=1, c=6.
7. The scintillator of claim 6 , wherein the activator comprises a cerium halide.
8. A method for manufacturing a scintillator, the method comprising:
manufacturing a matrix material comprising thallium, lanthanum, and a halogen element; and
doping the matrix material with an activator.
9. The method for manufacturing a scintillator of claim 8 , wherein the manufacturing of the matrix material comprises adding a thallium halide and a lanthanum halide in a molar ratio of 1:2, 2:1, or 3:1.
10. The method for manufacturing a scintillator of claim 8 , wherein the doping of the activator comprises doping the matrix material with a cerium halide.
11. The method for manufacturing a scintillator of claim 8 , wherein the halogen element comprises at least one among Cl, Br and I.
12. The method for manufacturing a scintillator of claim 8 , further comprising growing a mixture of the matrix material and the activator into a single crystal, wherein
the growing the mixture into the single crystal comprises descending an ampoule in which the mixture is sealed in a Bridgman electric furnace while heating the ampoule, wherein in the growing the mixture into the single crystal:
the crystal is grown while the ampoule is lowered in the Bridgman electric furnace at a crystal growing part;
a product of a descent speed of the ampoule in the Bridgman electric furnace and a temperature gradient at the crystal growing part in the Bridgman electric furnace is set to a range of 0.2-0.3° C./hr; and
the temperature gradient at the crystal growing part is a rate of an amount of a temperature change with respect to a positional change at a crystal growing position in the Bridgman electric furnace.
13. The method for manufacturing a scintillator of claim 12 , wherein in the growing the mixture of the matrix material and the activator into the single crystal, a melting temperature of the mixture is 450-650° C.