IP Library › Granted Patent US 10,131,598
Granted Patent B2
US 10,131,598 · App. 15/512,446 · Granted Nov 20, 2018

Polyfluoroalkyl allyl compound and method for producing the same

Inventor: Takeshi Fukushima (Ibaraki, JP)
Assignee: NOK Corporation
C07C21/18C07C17/363C07C67/293C07C69/63
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Quick Facts
Patent No.
US 10,131,598
App. No.
15/512,446
Granted
Nov 20, 2018
Kind
B2
Abstract

A polyfluoroalkyl allyl compound represented by the general formula: CF 3 (CF 2 ) n (CH 2 CF 2 ) a (CF 2 CF 2 ) b CH 2 CH═CH 2   [I] (n: 0 to 5, a: 1 or 2, b: 0 to 3). The polyfluoroalkyl allyl compound is produced by reacting a carboxylic acid allyl adduct represented by the general formula: CF 3 (CF 2 ) n (CH 2 CF 2 ) a (CF 2 CF 2 ) b CH 2 CHICH 2 OCOR′  [II] (n, a, and b are as defined above, and R′: a C 1 -C 3 alkyl group) with a transition metal. This method for producing provides a polyfluoroalkyl allyl compound used as a synthetic intermediate for a fluorine-containing alkylsilane compound that can remove free iodine derived from the raw material compound, before a hydrosilylation reaction is performed, without using a metal reagent having a high environmental impact, and that has excellent handling properties.

Claims (6)

1. A polyfluoroalkyl allyl compound of the general formula:

CF 3 (CF 2 ) n (CH 2 CF 2 ) a (CF 2 CF 2 ) b CH 2 CH═CH 2   [I]

wherein n is an integer of 0 to 5, a is 1 or 2, b is an integer of 0 to 3.

2. A method for producing the polyfluoroalkyl allyl compound according to claim 1 , the method comprising reacting a carboxylic acid allyl adduct of the general formula:

CF 3 (CF 2 ) n (CH 2 CF 2 ) a (CF 2 CF 2 ) b CH 2 CHICH 2 OCOR′  [II]

wherein n is an integer of 0 to 5, a is 1 or 2, b is an integer of 0 to 3, and R′ is a C 1 -C 3 alkyl group, with a transition metal.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2017
From: FUKUSHIMA, TAKESHI
To: UNIMATEC CO., LTD.
Reel/Frame 041702/0764 →
Priority Claims (1)
JP 2014-200045 · Sep 30, 2014 · national
Continuity (1)
Related Publication 20170291865A1 · Oct 12, 2017