Polymer nanocomposites
Provided herein is technology relating to polymer nanocomposites, and particularly, but not exclusively, to polymer nanocomposites comprising two or more nanomaterials and methods of producing nanocomposites comprising two or more nanomaterials.
1. A method of making a polymer nanocomposite containing a solvent coexfoliated mixture of pristine nanomaterials comprising two or more distinctly different particle morphologies, said method comprising the steps of:
a) exfoliating a pristine nanomaterial by solvent exfoliation to produce a first solution or stable dispersion of a first exfoliated pristine nanomaterial;
b) exfoliating one or more additional pristine nanomaterials of different particle morphology from the first exfoliated pristine nanomaterial with the first solution or stable dispersion of the first pristine exfoliated nanomaterial to provide a second solution or stable dispersion containing a coexfoliated mixture of pristine nanomaterials in a highly exfoliated state;
c) introducing the second solution or stable dispersion into a polymer matrix; and
d) removing solvents from said matrix to provide a polymer nanocomposite;
wherein said coexfoliated mixture of pristine nanomaterials is dispersed in said polymer nanocomposite to form a nanodispersion; and wherein steps (b) and (c) are carried out by high shear mixing.
2. The method of claim 1 , wherein the coexfoliated mixture of pristine nanomaterials comprises pristine graphene nanoplatelets and pristine carbon nanotubes.
3. The method of claim 1 , wherein a ratio of the first exfoliated pristine nanomaterial to the one or more additional pristine nanomaterials is 1:60 to 60:1, inclusive.
4. The method of claim 1 , wherein said solvent is N-alkyl-pyrrolidone.