Polycarbonate resin composition and molded article comprising the same
A polycarbonate resin composition and a molded article using the same is disclosed. The polycarbonate resin composition includes a polycarbonate resin (A); a rubber-modified aromatic vinyl copolymer (B); and an additive for laser directed structuring (C). The polycarbonate resin composition has a heat deflection temperature (HDT) of about 100° C. or more.
1. A polycarbonate resin composition comprising:
100 parts by weight of a polycarbonate resin (A);
about 9 parts by weight to about 31 parts by weight of a rubber-modified aromatic vinyl copolymer (B);
about 10 parts by weight to about 12 parts by weight of an additive for laser directed structuring (C); and
about 2.5 parts to about 32 parts by weight of an aromatic vinyl copolymer (D),
wherein the composition has a heat deflection temperature (HDT) of 126° C. to 136° C.,
wherein a molded article comprising the polycarbonate resin composition has an impact strength (⅛″ notched) measured in accordance with ASTM D256 of about 51 kgf·cm/cm to about 59 kgf·cm/cm and a melt index (250° C., 10 kg) measured in accordance with ASTM D1238 of about 24 g/10 min to about 32 g/10 min.
2. The polycarbonate resin composition according to claim 1 , wherein the rubber-modified aromatic vinyl copolymer (B) includes a rubber polymer having an average diameter of about 200 nm to about 400 nm, and
wherein the rubber polymer is present in an amount of about 10 parts by weight to about 70 parts by weight, based on about 100 parts by weight of the rubber-modified aromatic vinyl copolymer (B).
3. The polycarbonate resin composition according to claim 1 , wherein the additive for laser directed molding (C) includes a metal oxide.
4. The polycarbonate resin composition according to claim 1 , wherein the additive for laser directed structuring (C) includes one or more of a copper (Cu)-containing metal oxide, a zinc (Zn)-containing metal oxide, a chromium (Cr)-containing metal oxide, a tin (Sn)-containing metal oxide, a magnesium (Mg)-containing metal oxide, an aluminium (Al)-containing metal oxide, a gold (Au)-containing metal oxide, a silver (Ag)-containing metal oxide, a cadmium (Cd)-containing metal oxide, a manganese (Mn)-containing metal oxide, a nickel (Ni)-containing metal oxide, a cobalt (Co)-containing metal oxide, a titanium (Ti)-containing metal oxide, and an iron (Fe)-containing metal oxide.
5. The polycarbonate resin composition according to claim 3 , wherein the metal oxide has a spinel structure.
6. The polycarbonate resin composition according to claim 1 , comprising the polycarbonate resin (A) and the aromatic vinyl copolymer (D) at a weight ratio of 3.1:1 to about 40:1.
7. The polycarbonate resin composition according to claim 1 , wherein the aromatic vinyl copolymer (D) is a copolymer of an aromatic vinyl monomer and a monomer copolymerizable with the aromatic vinyl monomer,
wherein the aromatic vinyl monomer includes one or more of styrene, α-methyl styrene, a halogen-substituted styrene and an alkyl-substituted styrene, and
wherein the monomer copolymerizable with the vinyl monomer includes one or more of acrylonitrile, ethacrylonitrile, α-chloro acrylonitrile, and fumaronitrile.
8. A molded article comprising the polycarbonate resin composition according to claim 1 .
9. The molded article according to claim 8 , wherein the molded article has a surface in which a plating pattern is entirely or partially formed.