Electroluminescent display device and manufacturing method thereof
View Patent ↗A highly reliable display device or electronic device is provided. The display device includes a first electrode, a second electrode, a light-emitting layer between the first electrode and the second electrode, and a protective film over the second electrode. The protective film includes a first insulating film and a second insulating film over the first insulating film. The first insulating film includes one or more of aluminum oxide, hafnium oxide, and zirconium oxide, and the second insulating film includes one or more of aluminum oxide, hafnium oxide, and zirconium oxide. A composition of the first insulating film is different from a composition of the second insulating film. A water vapor transmission rate of the protective film is lower than 1×10 −2 g/(m 2 ·day).
1. A display device comprising:
a first electrode;
a second electrode;
a light-emitting layer between the first electrode and the second electrode; and
a protective film over the second electrode,
wherein the protective film comprises a first insulating film and a second insulating film over the first insulating film,
wherein the first insulating film comprises one or more of aluminum oxide, hafnium oxide, and zirconium oxide,
wherein the second insulating film comprises one or more of aluminum oxide, hafnium oxide, and zirconium oxide, and
wherein a water vapor transmission rate of the protective film is lower than 1×10 −2 g/(m 2 ·day) under a condition of 40° C. and a relative humidity of 90%.
2. The display device according to claim 1 ,
wherein a composition of the first insulating film is different from a composition of the second insulating film.
3. The display device according to claim 1 ,
wherein the second insulating film has a higher carbon content than the first insulating film.
4. The display device according to claim 1 , further comprising a color film in contact with the second insulating film.
5. The display device according to claim 1 , further comprising a first display element,
wherein the first display element is a light-emitting element comprising the first electrode, the second electrode, and the light-emitting layer between the first electrode and the second electrode.
6. The display device according to claim 1 ,
wherein the second insulating film is formed by an atomic layer deposition method.
7. A display device comprising:
a first electrode;
a third insulating film overlapping with an edge portion of the first electrode;
a light-emitting layer over the first electrode and the third insulating film;
a second electrode over the light-emitting layer; and
a protective film over the second electrode,
wherein the protective film comprises a first insulating film and a second insulating film over the first insulating film,
wherein the first insulating film comprises one or more of aluminum oxide, hafnium oxide, and zirconium oxide,
wherein the second insulating film comprises one or more of aluminum oxide, hafnium oxide, and zirconium oxide,
wherein the first insulating film comprises a first region overlapping with the first electrode with the light-emitting layer positioned therebetween and a second region overlapping with the third insulating film with the light-emitting layer positioned therebetween,
wherein the second region comprises a region having a lower film density than the first region, and
wherein a water vapor transmission rate of the protective film is lower than 1×10 −2 g/(m 2 ·day) under a condition of 40° C. and a relative humidity of 90%.
8. The display device according to claim 7 ,
wherein part of the second insulating film fills part of the first insulating film.
9. The display device according to claim 7 ,
wherein a composition of the first insulating film is different from a composition of the second insulating film.
10. The display device according to claim 7 ,
wherein the second insulating film has a higher carbon content than the first insulating film.
11. The display device according to claim 7 , further comprising a color film in contact with the second insulating film.
12. The display device according to claim 7 , further comprising a first display element,
wherein the first display element is a light-emitting element comprising the first electrode, the second electrode, and the light-emitting layer between the first electrode and the second electrode.
13. The display device according to claim 7 , further comprising a first display element and a second display element,
wherein the first display element is a light-emitting element comprising the first electrode, the second electrode, and the light-emitting layer between the first electrode and the second electrode, and
wherein the second display element is a liquid crystal element.
14. The display device according to claim 7 ,
wherein the second insulating film is formed by an atomic layer deposition method.
15. A method for manufacturing a display device, comprising the steps of:
forming a light-emitting element comprising a light-emitting layer;
forming a first insulating film comprising one or more of aluminum oxide, hafnium oxide, and zirconium oxide over the light-emitting element by a sputtering method; and
forming the second insulating film comprising one or more of aluminum oxide, hafnium oxide, and zirconium oxide over the first insulating film by an atomic layer deposition method.
16. The method for manufacturing a display device according to claim 15 , further comprising a step of forming a color film over the second insulating film.