IP Library › Granted Patent US 10,145,027
Granted Patent B2
US 10,145,027 · App. 14/771,275 · Granted Dec 4, 2018

Fiber comprising polyethylene blend

Inventors: Arnaldo Lorenzo (Rosharon, TX); Selim Bensason (Baech, CH); Jacquelyn A. Degroot (Sugar Land, TX)
Assignee: Dow Global Technologies LLC
D01F6/46C08L23/06D01D5/08D04H3/007D04H3/16
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Quick Facts
Patent No.
US 10,145,027
App. No.
14/771,275
Granted
Dec 4, 2018
Kind
B2
Abstract

The present disclosure is directed to a fiber that is composed of a polymeric blend including (i) 95 wt % to 99 wt % of a high density ethylene-based polymer having a Mw/Mn from 2.0 to 3.0 and (ii) from 5 wt % to 1 wt % of a low density ethylene-based polymer having a melt index from 5 g/10 min to 15 g/10 min. The fiber has a density from 1 denier to 2 denier and a 3% secant modulus from 8.5 g/denier to 20 g/denier.

Claims (28)

1. A fiber comprising:

a polymeric blend comprising

from 95 wt % to 99 wt % of a high density ethylene-based polymer having a M w /M n from 2.0 to 3.0;

from 5 wt % to 1 wt % of a low density ethylene-based polymer having a melt index from 5 g/10 min to 15 g/10 min wherein the low-density ethylene-based polymer is present to the exclusion of linear low density polyethylene; and

the fiber having a density from 1 denier to 2 denier and a 3% secant modulus from 8.5 g/denier to 20 g/denier.

2. The fiber of claim 1 having a 3% secant modulus from 10 g/denier to 20 g/denier.

3. The fiber of claim 1 having a ramp-to-break from 2600 mpm to 3200 mpm.

4. The fiber of claim 1 wherein the high density ethylene-based polymer has a density from greater than 0.930 g/cc to 0.96 g/cc and a melt index from 15 g/10 min to 20 g/10 min.

5. The fiber of claim 1 wherein the high density ethylene-based polymer has a Mz/Mw less than 2.0.

6. The fiber of claim 1 wherein the high density ethylene-based polymer has a zero-shear viscosity ratio greater than 1.1.

7. The fiber of claim 1 wherein the high density ethylene-based polymer has a vinyls/10 6 carbons of less than 100.

8. The fiber of claim 1 wherein the low density ethylene-based polymer has a density from 0.915 g/cc to 0.925 g/cc and a melt index from 5 g/10 min to 15 g/10 min.

9. The fiber of claim 1 wherein the fiber is a melt-spun fiber.

10. The fiber of claim 1 wherein the fiber has a density of 2 denier, a 3% secant modulus from 10 g/denier to 20 g/denier, a tensile strength from greater than 1.0 g/denier to 1.3 g/denier, and a ramp-to-break from 2600 mpm to 3200 mpm.

11. The fiber of claim 1 wherein the fiber has a heat of crystallization greater than 205 J/g.

12. A fabric comprising the fiber of claim 1 .

13. The fiber of claim 1 wherein the high density ethylene-based polymer is an ethylene/octene copolymer.

14. A fiber comprising:

a polymeric blend comprising

from 95 wt % to 99 wt % of a high density ethylene-based polymer having

(i) a M w /M n from 2.0 to 3.0;

(ii) a zero-shear viscosity ratio greater than 1.1;

from 5 wt % to 1 wt % of a low density ethylene-based polymer (LDPE) having a melt index from 5 g/10 min to 15 g/10 min, the LOPE present to the exclusion of linear low density polyethylene; and

the fiber having a density from 1 denier to 2 denier and a 3% secant modulus from 8.5 g/denier to 20 g/denier.

15. The fiber of claim 14 wherein the high density ethylene-based polymer has a Mz/Mw less than 2.0.

16. The fiber of claim 15 wherein the high density ethylene-based polymer has a density from greater than 0.930 g/cc to 0.96 g/cc and a melt index from 15 g/10 min to 20 g/10 min.

17. The fiber of claim 16 having a ramp-to-break from 2600 mpm to 3200 mpm.

18. The fiber of claim 17 wherein the high density ethylene-based polymer is an ethylene/octene copolymer.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 29, 2018
From: LORENZO, ARNALDO; DEGROOT, JACQUELYN A.
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 047341/0744 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 29, 2018
From: BENSASON, SELIM
To: DOW EUROPE GMBH
Reel/Frame 047341/0878 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 29, 2018
From: DOW EUROPE GMBH
To: THE DOW CHEMICAL COMPANY
Reel/Frame 047341/0991 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 29, 2018
From: THE DOW CHEMICAL COMPANY
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 047342/0143 →
Continuity (2)
Provisional Application 61776379 · Mar 11, 2013
Related Publication 20160017518A1 · Jan 21, 2016