Organic electroluminescent compound and organic electroluminescent device
The present invention provides an organic electroluminescent compound and an organic electroluminescent device using the organic electroluminescent compound, the compound has the following structural formula: wherein R 1 , R 2 and R 4 are, each independently, selected from a group consisting of a hydrogen atom, a C1-C20 linear or branched alkyl group, a substituted or unsubstituted N-(phenylmethyl)imino group, a phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, a pyridyl group, a pyrimidinyl group, a quinolinyl group and a triazinyl group; R 3 is selected from a group consisting of hydrogen atom, a C1-C10 linear or branched alkyl group, a substituted or unsubstituted N-(phenylmethyl)imino group, a phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, a pyridyl group, a pyrimidinyl group, a quinolinyl group and a triazinyl group.
1. An organic electroluminescent compound having the following structural formula:
wherein R 1 , R 2 and R 4 are, each independently, selected from a group consisting of hydrogen, a C1-C20 linear or branched alkyl group, a substituted or unsubstituted N-(phenylmethyl)imino group, a phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, a pyridyl group, a pyrimidinyl group, a quinolyl group and a triazinyl group;
R 3 is selected from a group consisting of hydrogen, a C1-C10 linear or branched alkyl group, a substituted or unsubstituted N-(phenylmethyl)imino group, a phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, a pyridyl group, a pyrimidinyl group, a quinolyl group and a triazinyl group;
wherein R 1 , R 2 , R 3 and R 4 being all hydrogen or C4 branched alkyl group is excluded.
2. The organic electroluminescent compound according to claim 1 , wherein among R 1 , the N-(phenylmethyl)imino group, the phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, the pyridyl group, the pyrimidinyl group, the quinolyl group or the triazinyl group, at least one hydrogen atom thereof is substituted with a C1-C20 linear or branched alkyl group, a C3-C24 cyclic alkyl group, a C1-C20 alkoxyl group, halogen, CN, CF 3 , Si(CH 3 ) 3 , or a C6-C50 aryl group.
3. The organic electroluminescent compound according to claim 1 , wherein among R 2 , the N-(phenylmethyl)imino group, the phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, the pyridyl group, the pyrimidinyl group, the quinolyl group and the triazinyl group, at least one hydrogen atom thereof is substituted with a C1-C20 linear or branched alkyl group, a C3-C24 cyclic alkyl group, a C1-C20 alkoxyl group, halogen, CN, CF 3 , Si(CH 3 ) 3 , a naphthyl group, an anthryl group, a phenanthryl group, dibenzofuran, a fluorenyl group, a carbazolyl group, spiro fluorene, or a heteroaryl group having 5-20 non-H atoms.
4. The organic electroluminescent compound according to claim 1 , wherein among R 3 , the N-(phenylmethyl)imino group, the phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, the pyridyl group, the pyrimidinyl group, the quinolinyl group or the triazinyl group, at least one hydrogen atom thereof is substituted with a C1-C10 linear or branched alkyl group, a C3-C12 cyclic alkyl group, a C1-C10 alkoxyl group, halogen, CN, CF 3 , Si(CH 3 ) 3 , or a C6-C30 aryl group.
5. The organic electroluminescent compound according to claim 1 , wherein among R 4 , the N-(phenylmethyl)imino group, the phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, the pyridyl group, the pyrimidinyl group, the quinolyl group and the triazinyl group, at least one hydrogen atom thereof is substituted with a C1-C10 linear or branched alkyl group, a C3-C12 cyclic alkyl group, a C1-C10 alkoxyl group, halogen, CN, CF 3 , Si(CH 3 ) 3 , a naphthyl group, an anthryl group, a phenanthryl group, dibenzofuran, a fluorenyl group, a carbazolyl group, spiro fluorene, or a heteroaryl group having 5-20 non-H atoms.
6. The organic electroluminescent compound according to claim 1 , wherein the organic electroluminescent compound is any one of following compounds:
7. An organic electroluminescent device, comprising the organic electroluminescent compound,
wherein the organic electroluminescent compound has the following structural formula:
wherein R 1 , R 2 and R 4 are, each independently, selected from a group consisting of hydrogen, a C1-C20 linear or branched alkyl group, a substituted or unsubstituted N-(phenylmethyl)imino group, a phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, a pyridyl group, a pyrimidinyl group, a quinolyl group and a triazinyl group;
R 3 is selected from a group consisting of hydrogen, a C1-C10 linear or branched alkyl group, a substituted or unsubstituted N-(phenylmethyl)imino group, a phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, a pyridyl group, a pyrimidinyl group, a quinolyl group and a triazinyl group;
wherein R 1 , R 2 , R 3 and R 4 being all hydrogen or C4 branched alkyl group is excluded.
8. The organic electroluminescent device according to claim 7 , wherein among R 1 , the N-(phenylmethyl)imino group, the phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, the pyridyl group, the pyrimidinyl group, the quinolyl group or the triazinyl group, at least one hydrogen atom thereof is substituted with a C1-C20 linear or branched alkyl group, a C3-C24 cyclic alkyl group, a C1-C20 alkoxyl group, halogen, CN, CF 3 , Si(CH 3 ) 3 , or a C6-C50 aryl group.
9. The organic electroluminescent device according to claim 7 , wherein among R 2 , the N-(phenylmethyl)imino group, the phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, the pyridyl group, the pyrimidinyl group, the quinolyl group and the triazinyl group, at least one hydrogen atom thereof is substituted with a C1-C20 linear or branched alkyl group, a C3-C24 cyclic alkyl group, a C1-C20 alkoxyl group, halogen, CN, CF 3 , Si(CH 3 ) 3 , a naphthyl group, an anthryl group, a phenanthryl group, dibenzofuran, a fluorenyl group, a carbazolyl group, spiro fluorene, or a heteroaryl group having 5-20 non-H atoms.
10. The organic electroluminescent device according to claim 7 , wherein among R 3 , the N-(phenylmethyl)imino group, the phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, the pyridyl group, the pyrimidinyl group, the quinolinyl group or the triazinyl group, at least one hydrogen atom thereof is substituted with a C1-C10 linear or branched alkyl group, a C3-C12 cyclic alkyl group, a C1-C10 alkoxyl group, halogen, CN, CF 3 , Si(CH 3 ) 3 , or a C6-C30 aryl group.
11. The organic electroluminescent device according to claim 7 , wherein among R 4 , the N-(phenylmethyl)imino group, the phenyl group, phenylamine, diphenylamine, phenyl pyridinylamine, bipyridinylamine, phenyl naphthylamine, binaphthylamine, phenyl phenanthrylamine, biphenanthrylamine, phenyl anthrylamine, bianthrylamine, phenanthridine, biphenyl, the pyridyl group, the pyrimidinyl group, the quinolyl group and the triazinyl group, at least one hydrogen atom thereof is substituted with a C1-C10 linear or branched alkyl group, a C3-C12 cyclic alkyl group, a C1-C10 alkoxyl group, halogen, CN, CF 3 , Si(CH 3 ) 3 , a naphthyl group, an anthryl group, a phenanthryl group, dibenzofuran, a fluorenyl group, a carbazolyl group, spiro fluorene, or a heteroaryl group having 5-20 non-H atoms.
12. The organic electroluminescent device according to claim 7 , wherein the organic electroluminescent compound is any one of following compounds: