Method for recovering scandium
Provided is a method for recovering scandium with which scandium can be efficiently recovered as high purity scandium oxide from a scandium-containing solution containing impurities such as iron without causing problems such as increased cost and safety problems. According to the method for recovering scandium according to the present invention, the pH of a solution containing scandium and iron (scandium-containing solution) is adjusted within the range of not less than −0.5 and less than 1, then scandium oxalate is obtained by adding the pH adjusted solution to an oxalic acid solution, and the scandium oxalate is roasted into scandium oxide.
1. A method for recovering scandium, comprising:
adjusting pH of a solution containing scandium and iron to a range of 0.5 to less than 1 wherein the scandium-containing solution contains divalent iron ions;
adding the solution after the pH adjustment to an oxalic acid solution filled in a reaction vessel to obtain scandium oxalate; and
roasting the scandium oxalate to convert the scandium oxalate into scandium oxide.
2. The method for recovering scandium according to claim 1 , wherein the scandium-containing solution before the pH adjustment is obtained by subjecting a solution containing scandium to an ion exchange treatment and a solvent extraction treatment.
3. The method of recovering scandium according to claim 1 , wherein in adding the solution after the pH adjustment to the oxalic acid solution, when the amount of oxalic acid required to convert scandium into scandium oxalate is defined as 1 equivalence, the amount of the oxalic acid solution is set to be in the range of 1.4 equivalence to 2.0 equivalences of scandium contained in the scandium-containing solution.