High temperature conduit having a complex, three-dimensional configuration
Molded articles are disclosed having a complex three-dimensional shape. In one embodiment, the molded articles comprise tubular members formed through blow molding that have multiple linear sections separated by curved sections. The curved sections can include multiple angular displacements in multiple planes. The tubular members are molded from a polymer composition containing a high temperature polymer, such as a polymer having a melting point of greater than about 280° C., such as greater than about 290° C. In one embodiment, the tubular member includes at least three angular displacements of from about 60° to about 120°, such as from about 70° to about 110°.
1. An engine conduit for conveying fluids to or from an engine comprising:
a single piece tubular member having a wall surrounding a hollow passageway, wherein the wall has a wall thickness that, is substantially uniform over an entire length of the single piece tubular member, the wall thickness varying by no more than 50%, the tubular member consisting of a layer formed from a polymer composition, the polymer composition comprising:
a linear polyphenylene sulfide in an amount ranging from about 60% by weight to about 80% by weight,
a branched polyphenylene sulfide in an amount ranging from about 0.5% by weight to about 15% by weight;
reinforcing fibers in an amount ranging from about 10% by weight to about 25% by weight,
an impact modifier, wherein the impact modifier comprises a random copolymer of a polyolefin and glycidyl methacrylate and is present in an amount ranging from about 0.5% to about 10% by weight, wherein the glycidyl methacylate is present in an amount ranging from about 6% by weight to 10% by weight, and
a compatibilizer, wherein the compatibilizer comprises an organosilane,
wherein the polymer composition has a low shear rate storage modulus that is greater than 1500 Pa as determined at 310° C. and 0.1 rad/s; and
wherein the tubular member has a three-dimensional configuration including at least three linear sections separated by at least two angular displacements, the first angular displacement being from about 60° to about 120° when lying in a first plane, the second angular displacement also being from about 60° to about 120° and oriented such that the second angular displacement lies in a second plane that intersects with the first plane.
2. An engine conduit as defined in claim 1 , wherein the tubular member includes a curved section that defines the first angular displacement, the curved section also defining a third angular displacement that lies in a different plane than the first angular displacement.
3. An engine conduit as defined in claim 1 , wherein the tubular member includes at least three angular displacements, the third angular displacement also being from about 60° to about 120°.
4. An engine conduit as defined in claim 3 , wherein the tubular member includes at least four angular displacements.
5. An engine conduit as defined in claim 3 , wherein the first angular displacement, the second angular displacement, and the third angular displacement are all from about 80° to about 100°.
6. An engine conduit as defined in claim 1 , wherein the thermoplastic polymer has a melting point greater than 280° C.
7. An engine conduit as defined in claim 1 , wherein the polymer composition has a relatively high melt strength such that at 15° C. greater than the melting point of the thermoplastic polymer, the polymer composition displays an engineering stress of from about 350 kPa to about 550 kPa at 100% strain.
8. An engine conduit as defined in claim 1 , wherein the first angular displacement and the second angular displacement are from about 80° to about 100°.
9. An engine connected to the engine conduit defined in claim 1 .
10. A single piece tubular member comprising a wall surrounding a hollow passageway, wherein the wall has a wall thickness that is substantially uniform over an entire length of the single piece tubular member, the wall thickness varying by no more than 50%, the tubular member consisting of a layer formed from a polymer composition, the polymer composition comprising a linear polyphenylene sulfide in an amount ranging from about 60% by weight to about 80% by weight, a branched polyphenylene sulfide in an amount ranging from about 0.5% by weight to about 15% by weight, reinforcing fibers in an amount ranging from about 10% by weight to about 25% by weight, an impact modifier, wherein the impact modifier comprises a random copolymer of a polyolefin and glycidyl methacrylate and is present in an amount ranging from about 0.5% to about 10% by weight, wherein the glycidyl methacrylate is present in an amount ranging from about 6% by weight to 10% by weight, and a compatibilizer, wherein the compatibilizer comprises an organosilane, wherein the polymer composition has a low shear rate storage modulus that is greater than 1500 Pa as determined at 310° C. and 0.1 rad/s, the tubular member having a three-dimensional configuration including at least four linear sections separated by at least three angular displacements, the first angular displacement being from about 60° to about 120° and lying in a first plane, the second angular displacement also being from about 60° to about 120° and lying in a second plane, the third angular displacement also being from about 60° to about 120° and lying in a third plane, the first plane, the second plane, and the third plane all being different and wherein two planes intersect the remaining plane.
11. A tubular member as defined in claim 10 , wherein the polymer composition has a relatively high melt strength such that at 15° greater than the melting point of the thermoplastic polymer, the polymer composition displays an engineering stress of from about 350 kPa to about 550 kPa at 100% strain.